Thiolated, Reduced Palladium Nanoclusters with Resolved Structures for the Electrocatalytic Reduction of Oxygen

doi:10.1002/anie.202208751

	Thiolated, Reduced Palladium Nanoclusters with Resolved Structures for the Electrocatalytic Reduction of Oxygen
	Zhuang, Shengli 3,4,5; Chen, Dong 1; You, Qing 3,4,5; Fan, Wentao 2,3,4,5; Yang, Jun 1; Wu, Zhikun 3,4,5
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2022-10-18
关键词	Electrocatalysis Interstitial B Atom ORR Nanoclusters Palladium
ISSN号	1433-7851
DOI	10.1002/anie.202208751
通讯作者	Yang, Jun(jyang@ipe.ac.cn) ; Wu, Zhikun(zkwu@issp.ac.cn)
英文摘要	Although thiolated, reduced Group 11 metal nanoclusters with atomic monodispersity have been repeatedly reported in the past decade, their Pd analogues have not been reported thus far. In this work, we provide a resolution for the challenging synthesis and obtain for the first time an atomically monodisperse thiolated, reduced Pd (q=+0.75) nanocluster with a di-tetrahedron Pd-8 kernel and a +3 charged interstitial B atom, as revealed by ESI-MS, SCXRD, etc. mu-6 B is found for the first time in Group 10 and 11 metal nanoclusters. More importantly, the as-obtained Pd nanoclusters show better catalytic activity compared to 1.4 nm Pd nanoparticles, Pd-2 complexes and even a commercial Pt/C catalyst for the oxygen reduction reaction (ORR), having significant implications for the influence of the metal charge state and space structure on the catalytic activity.
资助项目	National Natural Science Foundation of China[21905284] ; National Natural Science Foundation of China[21829501] ; National Natural Science Foundation of China[21925303] ; National Natural Science Foundation of China[22075290] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21528303] ; China Postdoctoral Science Foundation[Y94G4E356B] ; Key Program of 13th five-year plan[KP-2017-16] ; Collaborative Innovation Program of Hefei Science Center, CAS[2020HSC-CIP005] ; Center for Mesoscience, Institute of Process Engineering, Chinese Academy of Sciences, State Key Laboratory of Multiphase Complex Systems[MPCS-2021-A-05]
WOS关键词	PROTECTED GOLD ; METAL BORIDE ; NANOPARTICLES ; SILVER ; CATALYSIS ; CLUSTERS
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000869649500001
资助机构	National Natural Science Foundation of China ; China Postdoctoral Science Foundation ; Key Program of 13th five-year plan ; Collaborative Innovation Program of Hefei Science Center, CAS ; Center for Mesoscience, Institute of Process Engineering, Chinese Academy of Sciences, State Key Laboratory of Multiphase Complex Systems
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/129464]
专题	中国科学院合肥物质科学研究院
通讯作者	Yang, Jun; Wu, Zhikun
作者单位	1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China 3.Chinese Acad Sci, CAS Ctr Excellence Nanosci, Inst Solid State Phys, Key Lab Mat Phys,Anhui Key Lab Nanomat & Nanotech, Hefei 230031, Peoples R China 4.Anhui Univ, Dept Chem, Hefei 230601, Anhui, Peoples R China 5.Anhui Univ, Ctr Atom Engn Adv Mat, Hefei 230601, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Zhuang, Shengli,Chen, Dong,You, Qing,et al. Thiolated, Reduced Palladium Nanoclusters with Resolved Structures for the Electrocatalytic Reduction of Oxygen[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022.
APA	Zhuang, Shengli,Chen, Dong,You, Qing,Fan, Wentao,Yang, Jun,&Wu, Zhikun.(2022).Thiolated, Reduced Palladium Nanoclusters with Resolved Structures for the Electrocatalytic Reduction of Oxygen.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Zhuang, Shengli,et al."Thiolated, Reduced Palladium Nanoclusters with Resolved Structures for the Electrocatalytic Reduction of Oxygen".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022).