The Role of NMR in Metal Organic Frameworks: Deep Insights into Dynamics, Structure and Mapping of Functional Groups | |
Rehman, Sajid Ur2; Xu, Shuai2,3; Xu, Huangtao2; Tao, Tongxiang2,4; Li, Yunyan2; Yu, Zhiwu2; Ma, Kun2; Xu, Weihong1; Wang, Junfeng2,4,5 | |
刊名 | MATERIALS TODAY ADVANCES |
2022-12-01 | |
卷号 | 16 |
关键词 | Metal organic frameworks NMR mapping of functional groups host-guest interaction |
ISSN号 | 2590-0498 |
DOI | 10.1016/j.mtadv.2022.100287 |
通讯作者 | Ma, Kun(makun@hmfl.ac.cn) ; Wang, Junfeng(junfeng@hmfl.ac.cn) |
英文摘要 | The fundamental understanding of metal-organic frameworks (MOFs) is crucial since the relationship between the macroscopic properties of these materials and their molecular-level structures allows for the development of technological applications and improvements in current performance. The metal centers and attached functional groups dictate MOFs' dynamics, structure, and porosity. The develop-ment of the solid-state nuclear magnetic resonance (SSNMR) technique, capable of providing atomic -level information, enables the non-destructive characterization of the structure and dynamics of MOFs have become essential step in ameliorating our understanding and are often complementary to tradi-tional methods. This review aims to briefly introduce the concepts of SSNMR and the methods employed when investigating the dynamics, structure, and mapping of functional groups of microporous materials, including MOFs. This review highlights the best experimental practices when working with these complex systems. The article scrutinizes the information on framework structures, active center, surface position, host-guest interaction, and intermediate interaction through different SSNMR spectrums. Despite all the recent technological advancements, the SSNMR still faces the challenges of large sample quantities, long experimental measurements and data analyses, and complex isotopic labeling, which are enlightened in this review.(c) 2022 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). |
资助项目 | National Natural Science Foundation of China[3190110313] ; National Natural Science Foundation of China[42177444] ; National Natural Science Foundation of China[U1932218] ; Chinese Academy of Sciences[YZJJ2022QN44] ; Alliance of International Science Organizations[ANSO-VF-2021-03] ; HFIPS Director's Fund[YZJJZX202014] |
WOS关键词 | SOLID-STATE NMR ; O-17 NMR ; SPECTROSCOPY ; MOLECULES ; TRANSFORMATION ; TRANSITION ; STABILITY ; CHEMISTRY ; PROTEINS ; BINDING |
WOS研究方向 | Materials Science |
语种 | 英语 |
出版者 | ELSEVIER |
WOS记录号 | WOS:000860494200002 |
资助机构 | National Natural Science Foundation of China ; Chinese Academy of Sciences ; Alliance of International Science Organizations ; HFIPS Director's Fund |
内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/129135] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Ma, Kun; Wang, Junfeng |
作者单位 | 1.Chinese Acad Sci, Inst Intelligent Machines, Hefei Inst Phys Sci, Anhui Prov Key Lab Biomimet Sensing & Adv Robot Te, Hefei 230031, Peoples R China 2.Chinese Acad Sci, Hefei Inst Phys Sci, CAS Key Lab High Magnet Field & Ion Beam Phys Biol, Hefei 230031, Anhui, Peoples R China 3.Chinese Acad Sci, Hefei Canc Hosp, Inst Hlth & Med Technol, Anhui Prov Key Lab Med Phys & Technol,Hefei Inst P, Hefei 230031, Anhui, Peoples R China 4.Univ Sci & Technol China, Hefei 230036, Anhui, Peoples R China 5.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Rehman, Sajid Ur,Xu, Shuai,Xu, Huangtao,et al. The Role of NMR in Metal Organic Frameworks: Deep Insights into Dynamics, Structure and Mapping of Functional Groups[J]. MATERIALS TODAY ADVANCES,2022,16. |
APA | Rehman, Sajid Ur.,Xu, Shuai.,Xu, Huangtao.,Tao, Tongxiang.,Li, Yunyan.,...&Wang, Junfeng.(2022).The Role of NMR in Metal Organic Frameworks: Deep Insights into Dynamics, Structure and Mapping of Functional Groups.MATERIALS TODAY ADVANCES,16. |
MLA | Rehman, Sajid Ur,et al."The Role of NMR in Metal Organic Frameworks: Deep Insights into Dynamics, Structure and Mapping of Functional Groups".MATERIALS TODAY ADVANCES 16(2022). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论