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Fabrication and electrochemical applications of the Co-embedded N&P-codoped hierarchical porous carbon host from yeast for Li-S batteries
Zhuang, Yan1,2; Ma, Jinglin1,3; Chen, Jingzhou4; Shi, Zhaojiao4; Leng, Feifan2; Feng, Wangjun1,4
刊名APPLIED SURFACE SCIENCE
2021-04-15
卷号545页码:-
关键词Yeast-based carbon SDS/Co synergistic activation Nitrogen and phosphorus codoping Hierarchical porous material Lithium-sulfur battery
ISSN号0169-4332
DOI10.1016/j.apsusc.2021.148936
英文摘要Many challenges stand in the way of the potential of Lithium-sulfur (Li-S) batteries, especially low conductivity and obvious shuttle effect. Among biomass materials, yeast is an ideal and natural precursor which is used to synthesize carbon materials. A novel method was deliberately developed to fabricate the Co-embedded N&P-codoped hierarchical porous yeast-based carbon (Co-YC) for Li-S batteries. Firstly, yeasts immersed by aqueous solution containing CoCl2 and sodium dodecylbenzene sulfonate (SDS) were freeze-dried, and then were pyrolyzed at 973 K for 3 h under the protection of argon. The as-prepared Co-YC materials with higher specific surface area (216.94 m(2) g(-1)) were finally used to load sulfur, suggesting that the meso/macroporous structure is helpful to avoiding the accumulation of sulfur on the surface of the materials. Subsequently the electrode equipped by Co-YC/S with a superior cycling stability and rate performance than YC/S has been successfully prepared. The obtained Co-YC/S electrode exhibited a better electrochemical performance, its discharge capacity reached 1462 mAh g(-1) at a rate of 0.1 C, and after 300 cycles, the stable reversible capacity was of 1010.8 mAh g(-1) at 0.2 C. The experimental results show that Co-YC/S can be a potential candidate for electrode material applied in Li-S batteries.
WOS研究方向Chemistry ; Materials Science ; Physics
语种英语
出版者ELSEVIER
WOS记录号WOS:000618316900003
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/147268]  
专题生命科学与工程学院
理学院
通讯作者Feng, Wangjun
作者单位1.Lanzhou Univ Technol, Coll Petrochem Engn, Lanzhou 730050, Peoples R China;
2.Lanzhou Univ Technol, Sch Life Sci & Engn, Lanzhou 730050, Peoples R China;
3.Lanzhou Univ Second Hosp, Orthopaed Key Lab Gansu Prov, Lanzhou 730030, Peoples R China;
4.Lanzhou Univ Technol, Sch Sci, Lanzhou 730050, Peoples R China
推荐引用方式
GB/T 7714
Zhuang, Yan,Ma, Jinglin,Chen, Jingzhou,et al. Fabrication and electrochemical applications of the Co-embedded N&P-codoped hierarchical porous carbon host from yeast for Li-S batteries[J]. APPLIED SURFACE SCIENCE,2021,545:-.
APA Zhuang, Yan,Ma, Jinglin,Chen, Jingzhou,Shi, Zhaojiao,Leng, Feifan,&Feng, Wangjun.(2021).Fabrication and electrochemical applications of the Co-embedded N&P-codoped hierarchical porous carbon host from yeast for Li-S batteries.APPLIED SURFACE SCIENCE,545,-.
MLA Zhuang, Yan,et al."Fabrication and electrochemical applications of the Co-embedded N&P-codoped hierarchical porous carbon host from yeast for Li-S batteries".APPLIED SURFACE SCIENCE 545(2021):-.
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