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Properties of a-C:H:Si thin films deposited by middle-frequency magnetron sputtering
Jiang, Jinlong1,2; Wang, Yubao1; Du, Jinfang1; Yang, Hua1; Hao, Junying3
刊名APPLIED SURFACE SCIENCE
2016-08-30
卷号379页码:516-522
关键词a-C:H:Si films Magnetron sputtering Structure Tribological properties
ISSN号0169-4332
DOI10.1016/j.apsusc.2016.04.014
英文摘要The silicon doped hydrogenated amorphous carbon (a-C:H:Si) films were prepared on silicon substrates by middle-frequency magnetron sputtering silicon target in an argon and methane gas mixture atmosphere. The deposition rate, chemical composition, structure, surface properties, stress, hardness and tribological properties in the ambient air of the films were systemically investigated using X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), atomic force microscopy (AFM), nanoindentation and tribological tester. The results show that doped silicon content in the films is controlled in the wide range from 39.7 at.% to 0.2 at.% by various methane gas flow rate, and methane flow rate affects not only the silicon content but also its chemical bonding structure in the films due to the transformation of sputtering modes. Meanwhile, the sp(3) carbon component in the films linearly increases with increasing of methane flow rate. The film deposited at moderate methane flow rate of 40-60 sccm exhibits the very smooth surface (RMS roughness 0.4 nm), low stress (0.42 GPa), high hardness (21.1 GPa), as well as low friction coefficient (0.038) and wear rate (1.6 x 10(-7) mm(3)/Nm). The superior tribological performance of the films could be attributed to the formation and integral covering of the transfer materials on the sliding surface and their high hardness. (C) 2016 Elsevier B.V. All rights reserved.
资助项目National Natural Science Foundation of China[51105186]
WOS研究方向Chemistry ; Materials Science ; Physics
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000376819300068
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/33628]  
专题理学院
省部共建有色金属先进加工与再利用国家重点实验室
通讯作者Jiang, Jinlong; Hao, Junying
作者单位1.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
2.Lanzhou Univ Technol, Sch Sci, Lanzhou 730050, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
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Jiang, Jinlong,Wang, Yubao,Du, Jinfang,et al. Properties of a-C:H:Si thin films deposited by middle-frequency magnetron sputtering[J]. APPLIED SURFACE SCIENCE,2016,379:516-522.
APA Jiang, Jinlong,Wang, Yubao,Du, Jinfang,Yang, Hua,&Hao, Junying.(2016).Properties of a-C:H:Si thin films deposited by middle-frequency magnetron sputtering.APPLIED SURFACE SCIENCE,379,516-522.
MLA Jiang, Jinlong,et al."Properties of a-C:H:Si thin films deposited by middle-frequency magnetron sputtering".APPLIED SURFACE SCIENCE 379(2016):516-522.
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