Novel coumarin-based pyrazoline derivatives organogels for Fe3+ detection and application in cell imaging | |
Yang, Yun-Shang1; Yang, Chen1; Zhang, Ying-Peng1; Guo, Hui-Chen2,3; Cao, Jing-Qi1; Xue, Ji-Jun4,5 | |
刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS |
2021-09-05 | |
卷号 | 624 |
关键词 | Coumarin Organogels Pyrazoline Iron ions |
ISSN号 | 0927-7757 |
DOI | 10.1016/j.colsurfa.2021.126798 |
英文摘要 | Two novel coumarin-based pyrazoline derivatives have been designed and synthesized as organogel factors. Organogelators Z1-2 both have gelation behavior in alcohol solution and DMSO. Gel-tert-butanol Z1-2 (CGC = 1.84%, 1.41%) fluoresce blue and yellow-green under ultraviolet irradiation, respectively. Z1-2 both exhibit selectivity for response to Fe3+ in THF-deionized aqueous (V: V = 9:1) solution, meanwhile display high sensitivity. Notably, introducing diethylamino at 7-position the coumarin unit increases the detection line range in Z2. Furthermore, Z2 not only has a good biocompatibility in living cells but also the sensing behavior of Fe3+ in the cell nucleus. The coordination mechanism of gelators Z1-2 and Fe3+ were performed at the DFT level. |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ELSEVIER |
WOS记录号 | WOS:000660291700008 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/148495] |
专题 | 石油化工学院 |
作者单位 | 1.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China; 2.Chinese Acad Agr Sci, Lanzhou Vet Res Inst, State Key Lab Vet Etiol Biol, Lanzhou 730046, Peoples R China; 3.Chinese Acad Agr Sci, Lanzhou Vet Res Inst, Natl Foot & Mouth Dis Reference Lab, Lanzhou 730046, Peoples R China; 4.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China; 5.Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Yun-Shang,Yang, Chen,Zhang, Ying-Peng,et al. Novel coumarin-based pyrazoline derivatives organogels for Fe3+ detection and application in cell imaging[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2021,624. |
APA | Yang, Yun-Shang,Yang, Chen,Zhang, Ying-Peng,Guo, Hui-Chen,Cao, Jing-Qi,&Xue, Ji-Jun.(2021).Novel coumarin-based pyrazoline derivatives organogels for Fe3+ detection and application in cell imaging.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,624. |
MLA | Yang, Yun-Shang,et al."Novel coumarin-based pyrazoline derivatives organogels for Fe3+ detection and application in cell imaging".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 624(2021). |
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