Barrierless HONO and HOS(O)(2)-NO2 Formation via NH3-Promoted Oxidation of SO2 by NO2 | |
Wang, Guoying1; Ma, Shangrong1; Niu, Xiuli2; Chen, Xuefu1; Liu, Fengshuo1; Li, Xin1; Li, Lan1; Shi, Gaofeng1; Wu, Zhijun3 | |
刊名 | JOURNAL OF PHYSICAL CHEMISTRY A |
2021 | |
卷号 | 125期号:12页码:2666-2672 |
ISSN号 | 1089-5639 |
DOI | 10.1021/acs.jpca.1c00539 |
英文摘要 | In the troposphere, the knowledge about nitrous acid (HONO) sources is incomplete. The missing source of sulfate and fine particles cannot be explained during haze events. Air quality models cannot predict high levels of secondary fine-particle pollution. Despite extensive studies, one challenging issue in atmospheric chemistry is identifying the source of HONO. Here, we present direct ab initio molecular dynamics simulation evidence and typical air pollution events of the formation of gaseous HONO, nitrogen dioxide/hydrogen sulfite (HOS(O)(2)-NO2 or NO2-HSO3) from nitrogen dioxide (NO2), sulfur dioxide (SO2), water (H2O), and ammonia (NH3) molecules in a proportion of 2:1:3:3. The reactions show a new mechanism for the formation of HONO and NO2-HSO3 in the troposphere, especially when the concentration of NO2, SO2, H2O, and NH3 is high (e.g., 2:1:3:3 or higher) in the air. Contrary to the proportion NO2, SO2, H2O, and NH3 equaling to 1:1:3:1 and 1:1:3:2, the proportion (2:1:3:3) enables barrierless reactions and weak interactions between molecules via the formation of HONO, NO2HSO3, and NH3/H2O. In addition, field observations are carried out, and the measured data are summarized. Correlation analysis supported the conversion of NO2 to HONO during observational studies. The weak interactions promote proton transfer, resulting in the generation of HONO, NO2-HSO3, and NH3/H2O pairs. |
WOS研究方向 | Chemistry ; Physics |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000636918400027 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/148280] |
专题 | 石油化工学院 |
作者单位 | 1.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China; 2.Gansu Food Inspect & Res Inst, Lanzhou 730050, Peoples R China; 3.Peking Univ, State Key Joint Lab Environm Simulat & Pollut Con, Coll Environm Sci & Engn, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Guoying,Ma, Shangrong,Niu, Xiuli,et al. Barrierless HONO and HOS(O)(2)-NO2 Formation via NH3-Promoted Oxidation of SO2 by NO2[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2021,125(12):2666-2672. |
APA | Wang, Guoying.,Ma, Shangrong.,Niu, Xiuli.,Chen, Xuefu.,Liu, Fengshuo.,...&Wu, Zhijun.(2021).Barrierless HONO and HOS(O)(2)-NO2 Formation via NH3-Promoted Oxidation of SO2 by NO2.JOURNAL OF PHYSICAL CHEMISTRY A,125(12),2666-2672. |
MLA | Wang, Guoying,et al."Barrierless HONO and HOS(O)(2)-NO2 Formation via NH3-Promoted Oxidation of SO2 by NO2".JOURNAL OF PHYSICAL CHEMISTRY A 125.12(2021):2666-2672. |
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