Promoting the electrocatalytic activity of platinum film for hydrogen evolution reaction by phosphorus doping | |
Zhao, Qiuping1; Qian, Qingyi1,2; Zhang, Bin2; Zhang, Xingkai2 | |
刊名 | MATERIALS CHEMISTRY AND PHYSICS |
2021 | |
卷号 | 263 |
关键词 | Platinum-phosphorus film Platinum film Electroless deposition Water splitting Hydrogen evolution reaction |
ISSN号 | 0254-0584 |
DOI | 10.1016/j.matchemphys.2021.124412 |
英文摘要 | The electrocatalytic performance of platinum film for HER is improved through phosphorus (P) doping. Platinum (Pt) and platinum-phosphorus (Pt?P) films are conveniently prepared on copper substrates through a modified electroless deposition strategy. The P doping, which is confirmed by EDS and XPS tests, can reduce the crystallinity of Pt and affect the electronic environment of Pt in the Pt-P film. Compared to the Pt film, the Pt-P film shows better electrocatalytic activity and stability for HER in 1.0 M KOH solution. The Pt-P film has the over-potential of 87.8 mV at a current density of 10 mA cm(-2), far below the Pt film with the corresponding over-potential of 254 mV. |
WOS研究方向 | Materials Science |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000630904700001 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/147408] |
专题 | 石油化工学院 |
作者单位 | 1.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China; 2.Chinese Acad Sci, Key Lab Sci & Technol Wear & Protect Mat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Qiuping,Qian, Qingyi,Zhang, Bin,et al. Promoting the electrocatalytic activity of platinum film for hydrogen evolution reaction by phosphorus doping[J]. MATERIALS CHEMISTRY AND PHYSICS,2021,263. |
APA | Zhao, Qiuping,Qian, Qingyi,Zhang, Bin,&Zhang, Xingkai.(2021).Promoting the electrocatalytic activity of platinum film for hydrogen evolution reaction by phosphorus doping.MATERIALS CHEMISTRY AND PHYSICS,263. |
MLA | Zhao, Qiuping,et al."Promoting the electrocatalytic activity of platinum film for hydrogen evolution reaction by phosphorus doping".MATERIALS CHEMISTRY AND PHYSICS 263(2021). |
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