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Promoting the electrocatalytic activity of platinum film for hydrogen evolution reaction by phosphorus doping
Zhao, Qiuping1; Qian, Qingyi1,2; Zhang, Bin2; Zhang, Xingkai2
刊名MATERIALS CHEMISTRY AND PHYSICS
2021
卷号263
关键词Platinum-phosphorus film Platinum film Electroless deposition Water splitting Hydrogen evolution reaction
ISSN号0254-0584
DOI10.1016/j.matchemphys.2021.124412
英文摘要The electrocatalytic performance of platinum film for HER is improved through phosphorus (P) doping. Platinum (Pt) and platinum-phosphorus (Pt?P) films are conveniently prepared on copper substrates through a modified electroless deposition strategy. The P doping, which is confirmed by EDS and XPS tests, can reduce the crystallinity of Pt and affect the electronic environment of Pt in the Pt-P film. Compared to the Pt film, the Pt-P film shows better electrocatalytic activity and stability for HER in 1.0 M KOH solution. The Pt-P film has the over-potential of 87.8 mV at a current density of 10 mA cm(-2), far below the Pt film with the corresponding over-potential of 254 mV.
WOS研究方向Materials Science
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000630904700001
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/147408]  
专题石油化工学院
作者单位1.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China;
2.Chinese Acad Sci, Key Lab Sci & Technol Wear & Protect Mat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
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GB/T 7714
Zhao, Qiuping,Qian, Qingyi,Zhang, Bin,et al. Promoting the electrocatalytic activity of platinum film for hydrogen evolution reaction by phosphorus doping[J]. MATERIALS CHEMISTRY AND PHYSICS,2021,263.
APA Zhao, Qiuping,Qian, Qingyi,Zhang, Bin,&Zhang, Xingkai.(2021).Promoting the electrocatalytic activity of platinum film for hydrogen evolution reaction by phosphorus doping.MATERIALS CHEMISTRY AND PHYSICS,263.
MLA Zhao, Qiuping,et al."Promoting the electrocatalytic activity of platinum film for hydrogen evolution reaction by phosphorus doping".MATERIALS CHEMISTRY AND PHYSICS 263(2021).
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