Hydrogen and CO2 storage in high surface area covalent triazine–based frameworks | |
Deng, Q.-W.1,4; Ren, G.-Q.1; Li, Y.-J.2,3; Yang, L.1,2; Zhai, S.-L.1; Yu, T.1; Sun, L.1; Deng, W.-Q.1,2; Li, A.5; Zhou, Y.-H.4 | |
刊名 | Materials Today Energy |
2020-12-01 | |
卷号 | 18 |
关键词 | Adsorption Carbon dioxide Hydrogen fuels Monte Carlo methods Adsorption mechanism Ambient conditions Annealing treatments CO2 adsorption Defects induced Grand canonical Monte carlo High adsorption capacity High surface area |
DOI | 10.1016/j.mtener.2020.100506 |
英文摘要 | Hydrogen storage and CO2 capture are of great importance for efficient fuel usage and environmentally clean methods. Here, we report a series of 7,7,8,8-tetracyanoquinodimethane-derived covalent triazine frameworks (TCNQ-CTFs) with different specific surface areas for hydrogen and CO2 storage. Such TCNQ-CTFs exhibit maximum H2 and CO2 adsorption capacities up to 2.79 wt% (77 K, 1 bar) and 5.99 mmol/g (273 K, 1 bar), respectively, which are the highest values among reported covalent triazine frameworks.Theory simulation by using the Grand Canonical Monte Carlo (GCMC) method revealed that abundant nitrogen and defects induced by annealing treatment are the reasons for the high adsorption capacity of the material. This work not only contributes a superior material for both hydrogen and CO2 storage under ambient conditions but also deepens the knowledge on its adsorption mechanism, thus guiding people to engineer more efficient storage materials. © 2020 Elsevier Ltd |
语种 | 英语 |
出版者 | Elsevier Ltd |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/115769] |
专题 | 石油化工学院 |
作者单位 | 1.Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao; 266237, China; 2.State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Dalian; 116023, China; 3.Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, 199 Ren'ai Road, Suzhou; Jiangsu; 215123, China 4.College of Hydraulic & Environmental Engineering, China Three Gorges University, Changyi; 443002, China; 5.College of Petrochemical Technology, Lanzhou University of Technology, Langongping Road 287, Lanzhou; 730050, China; |
推荐引用方式 GB/T 7714 | Deng, Q.-W.,Ren, G.-Q.,Li, Y.-J.,et al. Hydrogen and CO2 storage in high surface area covalent triazine–based frameworks[J]. Materials Today Energy,2020,18. |
APA | Deng, Q.-W..,Ren, G.-Q..,Li, Y.-J..,Yang, L..,Zhai, S.-L..,...&Zhou, Y.-H..(2020).Hydrogen and CO2 storage in high surface area covalent triazine–based frameworks.Materials Today Energy,18. |
MLA | Deng, Q.-W.,et al."Hydrogen and CO2 storage in high surface area covalent triazine–based frameworks".Materials Today Energy 18(2020). |
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