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Treating Simulated Dye Wastewater by an In Situ Copper Ferrite Process
Han, Zhi-Yong3; Han, Kun3; Hao, Hao-Tian1,4; Yu, Jian-Wei1,2; Shi, Bao-You1,2; Zhuang, Yuan1; Kong, Yan3
刊名Huanjing Kexue/Environmental Science
2018-03-15
卷号39期号:3页码:1195-1201
关键词Adsorption Aromatic compounds Azo dyes Binary alloys Catalytic oxidation Copper Copper alloys Dyes Iron alloys Magnetic materials Magnetic separation Molar ratio Recycling Thermodynamics Wastewater reclamation Wastewater treatment Copper ferrites Dyes wastewaters High-temperature calcination Operational parameters Physical interactions Reaction conditions Reaction temperature Reaction thermodynamics
ISSN号02503301
DOI10.13227/j.hjkx.201706099
英文摘要Four types of simulated dye wastewater containing methylene blue, tartrazine, Congo red, and crystal violet were treated by an in situ copper ferrite process, and the influencing factors of the operational parameters in this process were studied. The main mechanism of dye removal was suggested by reaction thermodynamics and solid products characterization for methylene blue removal. The results showed that an in situ copper ferrite process could effectively remove four kinds of simulated dyes by adjusting reaction conditions appropriately. The maximum capacities of the in situ copper ferrite process for methylene blue, crystal violet, tartrazine, and Congo red were 349.2, 382.2, 402.5 and 831.8 mg•g-1, respectively, under reaction condition of c(Cu2+) of 0.01 mol•L-1, c(Fe2+) of 0.025 mol•L-1, c(OH)/c(M)=1.7 (hydroxyl and metal molar ratio), reaction temperature of 40, and reaction time of 60 min. Comprehensive physical interactions, including a sweeping effect, encapsulation, and high active surface adsorption of the in situ Fe-Cu precipitates were the dominant mechanisms in dye removal by the process. Copper ferrite, as an effective magnetic adsorbent and a highly efficient environmental catalyst, was regenerated by magnetic separation, catalytic oxidation, and high temperature calcination. © 2018, Science Press. All right reserved.
语种中文
出版者Science Press
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/114963]  
专题石油化工学院
作者单位1.Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing; 100085, China;
2.University of Chinese Academy of Sciences, Beijing; 100049, China
3.College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou; 730050, China;
4.College of Environmental Science and Engineering, Beijing Forestry University, Beijing; 100083, China;
推荐引用方式
GB/T 7714
Han, Zhi-Yong,Han, Kun,Hao, Hao-Tian,et al. Treating Simulated Dye Wastewater by an In Situ Copper Ferrite Process[J]. Huanjing Kexue/Environmental Science,2018,39(3):1195-1201.
APA Han, Zhi-Yong.,Han, Kun.,Hao, Hao-Tian.,Yu, Jian-Wei.,Shi, Bao-You.,...&Kong, Yan.(2018).Treating Simulated Dye Wastewater by an In Situ Copper Ferrite Process.Huanjing Kexue/Environmental Science,39(3),1195-1201.
MLA Han, Zhi-Yong,et al."Treating Simulated Dye Wastewater by an In Situ Copper Ferrite Process".Huanjing Kexue/Environmental Science 39.3(2018):1195-1201.
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