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Thermophysical properties of three-dimensional palygorskite based composite phase change materials
Wang, Yi1,2; Song, Yanhui2; Li, Shuang2; Zhang, Ting2; Zhang, Deyi1,2; Guo, Pengran3
刊名APPLIED CLAY SCIENCE
2020-01
卷号184
关键词Thermal energy storage Functionalized palygorskite Pore size Structure-property relationship
ISSN号0169-1317
DOI10.1016/j.clay.2019.105367
英文摘要In order to enhance the loading capacity of palygorskite (Pal) and further understand the relationship between pore size of carrier and thermal properties of mineral-based phase change materials (PCMs), series of three-dimensional palygorskite carriers and corresponding composite PCMs (CPCMs) were fabricated. The morphology, structural characteristics and thermal properties of the support and composite PCMs were determined by various techniques. The effects of support microstructure on the thermo physical properties of CPCMs were also discussed. The results revealed that the isocyanate functionalized palygorskite can be covalently bonded by dihydric alcohol to form three-dimensional Pal-based carrier. The pore diameter of the carrier varies with the chain length of dihydric alcohol. Since covalent bonding and surface functionalization can prevent the agglomeration of palygorskite crystals, thermal energy storage performance of stearic acid/three-dimensional palygorskite is increased by 67.4% to 100.7% within the scope of the study compared with that of stearic acid/palygorskite. The phase change temperature and latent heat of the composite phase change material have a linear correlation with pore size of support. This study is expected to be helpful for designing mineral-based porous carrier and providing guidance for optimizing CPCMs.
资助项目National Natural Science Foundation of China[51562023] ; Research Fund Program of Guangdong Provincial Key Laboratory of Emergency Test for Dangerous Chemicals[KF2018001]
WOS研究方向Chemistry ; Materials Science ; Mineralogy
语种英语
出版者ELSEVIER
WOS记录号WOS:000510399100004
状态已发表
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/64167]  
专题石油化工学院
省部共建有色金属先进加工与再利用国家重点实验室
通讯作者Wang, Yi; Guo, Pengran
作者单位1.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
2.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
3.Guangdong Inst Anal, Guangdong Engn Technol Res Ctr On Line Monitoring, Guangdong Prov Key Lab Emergency Test Dangerous C, Guangzhou 510070, Peoples R China
推荐引用方式
GB/T 7714
Wang, Yi,Song, Yanhui,Li, Shuang,et al. Thermophysical properties of three-dimensional palygorskite based composite phase change materials[J]. APPLIED CLAY SCIENCE,2020,184.
APA Wang, Yi,Song, Yanhui,Li, Shuang,Zhang, Ting,Zhang, Deyi,&Guo, Pengran.(2020).Thermophysical properties of three-dimensional palygorskite based composite phase change materials.APPLIED CLAY SCIENCE,184.
MLA Wang, Yi,et al."Thermophysical properties of three-dimensional palygorskite based composite phase change materials".APPLIED CLAY SCIENCE 184(2020).
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