Synthesis, Characterization and Catalytic Applications of Hierarchically Porous Aluminophosphate Molecular Sieves

doi:10.7536/PC151141

CORC > 兰州理工大学 > 兰州理工大学 > 石油化工学院

	Synthesis, Characterization and Catalytic Applications of Hierarchically Porous Aluminophosphate Molecular Sieves
	Zhao Xinhong; Gao Xiangping; Hao Zhixin; Zhang Xiaoxiao
刊名	PROGRESS IN CHEMISTRY
	2016-05
卷号	28 期号:5 页码:686-696
关键词	hierarchically porous aluminophosphate zeolite template method post-synthesis method catalytic applications
ISSN号	1005-281X
DOI	10.7536/PC151141
英文摘要	Hierarchically porous aluminophosphate molecular sieves possessing both micropores and mesopores recently receive increasing interest because they can reduce diffusion limitations in the reactions involving bulky molecules. This paper mainly focuses on the latest development of synthesis, characterizations and catalytic applications of hierarchically porous aluminophosphate molecular sieves. According to the formation mechanism of hierarchical pores, the synthetic methods of the hierarchical structured aluminophosphate molecular sieves can be classified into four categories: hard template, soft template, nontemplated and post-synthesis method. The advantages and disadvantages of these synthetic methods are systematically compared with each other. From the point view of industrial application, the nontemplated and post-synthesis methods are more promising compared to other synthetic routes. In addition, various techniques characterizing the acid properties and pore textures of hierarchically porous molecular sieves are described, taking silicoaluminophosphate molecular sieve as an example. However, most of these measurements need to be performed on complex expensive instruments, and the process is time-consuming. Thus, to develop some facile and general characterization techniques is highly desirable. Finally, the catalytic applications of these hierarchically porous materials in three kinds of important reactions (such as alkylation reaction, isomerization reaction and, methanol to olefins) are reviewed. The relationships between the catalytic performances and the properties of catalysts are analyzed in detail.
资助项目	National Natural Science Foundation of China[21306072]
WOS研究方向	Chemistry
语种	中文
出版者	CHINESE ACAD SCIENCES
WOS记录号	WOS:000377640400009
状态	已发表
内容类型	期刊论文
源URL	[http://119.78.100.223/handle/2XXMBERH/33704]
专题	石油化工学院
通讯作者	Zhao Xinhong
作者单位	Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China
推荐引用方式 GB/T 7714	Zhao Xinhong,Gao Xiangping,Hao Zhixin,et al. Synthesis, Characterization and Catalytic Applications of Hierarchically Porous Aluminophosphate Molecular Sieves[J]. PROGRESS IN CHEMISTRY,2016,28(5):686-696.
APA	Zhao Xinhong,Gao Xiangping,Hao Zhixin,&Zhang Xiaoxiao.(2016).Synthesis, Characterization and Catalytic Applications of Hierarchically Porous Aluminophosphate Molecular Sieves.PROGRESS IN CHEMISTRY,28(5),686-696.
MLA	Zhao Xinhong,et al."Synthesis, Characterization and Catalytic Applications of Hierarchically Porous Aluminophosphate Molecular Sieves".PROGRESS IN CHEMISTRY 28.5(2016):686-696.