Fabrication of the phosphorus doped mesoporous carbon with superior capacitive performance by microwave irradiation under ambient atmosphere: An ultra-facile and energy-efficient method

doi:10.1016/j.apsusc.2018.07.089

CORC > 兰州理工大学 > 兰州理工大学 > 石油化工学院

	Fabrication of the phosphorus doped mesoporous carbon with superior capacitive performance by microwave irradiation under ambient atmosphere: An ultra-facile and energy-efficient method
	Li, Yubing 2; Zhang, Deyi 1,2; Han, Mei 2; He, Jingjing 2; Wang, Yulin 2; Wang, Kunjie 2; Wang, Yi 2
刊名	APPLIED SURFACE SCIENCE
	2018-11-15
卷号	458 页码:119-128
关键词	Microwave irradiation Mesoporous carbons Phosphorus doping Supercapacitor
ISSN号	0169-4332
DOI	10.1016/j.apsusc.2018.07.089
英文摘要	This paper reports an ultra-facile and energy-efficient microwave irradiation method for fabrication of phosphorus doped mesoporous carbon under ambient atmosphere. The fabricated phosphorus doped mesoporous carbons exhibit high specific surface area (up to 2055 m(2) g(-1)), large pore volume (up to 2.73 cm(3) g(-1)) and good conductivity, which specific capacitance reaches up to 210 F g(-1), over 201 F g(-1) of capacitance is retained even under a high current density of 20 A g(-1), and the capacitance retention arrives 97.39% after 10,000 times charge/discharge cycles. Comparative study reveals that similar morphology is obtained by microwave irradiation and traditional pyrolytic carbonization, but more developed porosity and higher graphitization degree are achieved under microwave irradiation. The carbonization process completes in 1-3 min under microwave irradiation, which generally spends more than 2 h at a high temperature of over 600 degrees C by traditional pyrolytic method. No dramatic increase for surface oxygen content is found even it was fabricated under ambient atmosphere. The samples fabricated under microwave irradiation are potentially cost-efficient and high-performance electrode material for commercial supercapacitors.
资助项目	National Natural Science Foundation of China[51462020] ; Foundation for Innovation Groups of Basic Research in Gansu Province[1606RJIA322]
WOS研究方向	Chemistry ; Materials Science ; Physics
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000441400000015
状态	已发表
内容类型	期刊论文
源URL	[http://119.78.100.223/handle/2XXMBERH/32336]
专题	石油化工学院省部共建有色金属先进加工与再利用国家重点实验室
通讯作者	Zhang, Deyi
作者单位	1.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China 2.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式 GB/T 7714	Li, Yubing,Zhang, Deyi,Han, Mei,et al. Fabrication of the phosphorus doped mesoporous carbon with superior capacitive performance by microwave irradiation under ambient atmosphere: An ultra-facile and energy-efficient method[J]. APPLIED SURFACE SCIENCE,2018,458:119-128.
APA	Li, Yubing.,Zhang, Deyi.,Han, Mei.,He, Jingjing.,Wang, Yulin.,...&Wang, Yi.(2018).Fabrication of the phosphorus doped mesoporous carbon with superior capacitive performance by microwave irradiation under ambient atmosphere: An ultra-facile and energy-efficient method.APPLIED SURFACE SCIENCE,458,119-128.
MLA	Li, Yubing,et al."Fabrication of the phosphorus doped mesoporous carbon with superior capacitive performance by microwave irradiation under ambient atmosphere: An ultra-facile and energy-efficient method".APPLIED SURFACE SCIENCE 458(2018):119-128.