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A novel chromone derivative as dual probe for selective sensing of Al(III) by fluorescent and Cu(II) by colorimetric methods in aqueous solution
Tian, Limei1; Xue, Jia1; Li, Si-liang2; Yang, Zheng-yin1
刊名JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
2019-09
卷号382
关键词Fluorescent probe Chromone derivative Cu2+ Al3+ Colorimerric probe
ISSN号1010-6030
DOI10.1016/j.jphotochem.2019.111955
英文摘要Based on the chromone skeleton, a simple and novel probe that is 6-ethoxychromone-3-carbaldehyde-(furanyl) hydrazone (L) has been synthesized and completely characterized. It exhibited representative turn-on fluorescent properties and obviously colorimetric changes with high selectivity to Al3+ and Cu2+. For Al3+, L displayed a turn on green fluorescence in EtOH/H2O (3/2) aqueous media over other common cations. With Cu2+, L perceived Cu2+ through the naked-eye by the color changed-from colorless to yellow. Moreover, the co-ordination ratio between L-Al3+ and L-Cu2+ was 1:1 which could be verified by the Job's plot, H-1 NMR and high-resolution mass spectrum. Consequentially, L could be used as a solid probe for both Al3+ and Cu2+.
资助项目National Natural Science Foundation of China[21761019]
WOS研究方向Chemistry
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000481566700063
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/31602]  
专题石油化工学院
通讯作者Yang, Zheng-yin
作者单位1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
2.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Gansu, Peoples R China
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Tian, Limei,Xue, Jia,Li, Si-liang,et al. A novel chromone derivative as dual probe for selective sensing of Al(III) by fluorescent and Cu(II) by colorimetric methods in aqueous solution[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,2019,382.
APA Tian, Limei,Xue, Jia,Li, Si-liang,&Yang, Zheng-yin.(2019).A novel chromone derivative as dual probe for selective sensing of Al(III) by fluorescent and Cu(II) by colorimetric methods in aqueous solution.JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,382.
MLA Tian, Limei,et al."A novel chromone derivative as dual probe for selective sensing of Al(III) by fluorescent and Cu(II) by colorimetric methods in aqueous solution".JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 382(2019).
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