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Effect of surface orientation on reactive wetting of sapphire by Al-Ti alloys at 1273 K
Sui, Ran1; Chang, Jinghuan1; Lin, Qiaoli2
刊名MATERIALS CHEMISTRY AND PHYSICS
2022-06-01
卷号285
关键词Wettability Anisotropy Interfacial energy Surface
ISSN号0254-0584
DOI10.1016/j.matchemphys.2022.126187
英文摘要The effect of surface orientation on the reactive wetting of sapphire by Al-Ti alloys was studied by the modified sessile drop method at 1273 K under a high vacuum atmosphere. The monocrystal alpha-Al2O3 (sapphire) substrates with different atomic termination surfaces were selected in this study, i.e., C (0,0,0,1), R (1 1(-),0,2), and M (1 1( -),0,0) faces. The order of wettability is R > C asymptotic to polycrystalline substrate > M, and the final contact angles are 65 +/-& nbsp;0.1 (R), 76 +/-& nbsp;0.2 (C), 76 +/-& nbsp;0.3 (polycrystalline), and 84 +/-& nbsp;0.3 (M), respectively. The addition of Ti does not result in the formation of the continuous reaction layer, but it may contribute to the reaction of 4Al(l)+ Al2O3 (s)-> 3Al2O(g)up arrow & nbsp;. When the interfacial bonding is mainly chemical, the wettability depends on the bonding energy between the terminal atoms of the crystal face and the atoms of the liquid phase. The higher the bonding energy, the better the wettability.
WOS研究方向Materials Science
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000800427000002
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/158670]  
专题材料科学与工程学院
作者单位1.Lanzhou Inst Technol, Dept Mat Sci & Engn, 1 Gongjiaping East Rd, Lanzhou 730050, Peoples R China;
2.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, 287 Langongping Rd, Lanzhou 730050, Peoples R China
推荐引用方式
GB/T 7714
Sui, Ran,Chang, Jinghuan,Lin, Qiaoli. Effect of surface orientation on reactive wetting of sapphire by Al-Ti alloys at 1273 K[J]. MATERIALS CHEMISTRY AND PHYSICS,2022,285.
APA Sui, Ran,Chang, Jinghuan,&Lin, Qiaoli.(2022).Effect of surface orientation on reactive wetting of sapphire by Al-Ti alloys at 1273 K.MATERIALS CHEMISTRY AND PHYSICS,285.
MLA Sui, Ran,et al."Effect of surface orientation on reactive wetting of sapphire by Al-Ti alloys at 1273 K".MATERIALS CHEMISTRY AND PHYSICS 285(2022).
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