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Towards tailorable interface microstructure through Solid-state interface reaction between synthetic diamond grits and sputtered Ni-Cr binary alloy
Cheng, Wei2; Liu, Zhuo2; Lin, Qiaoli1; Huang, Guoqin2; Xu, Xipeng2; Huang, Han3; Mu, Dekui2
刊名Applied Surface Science
2022-09-15
卷号596
关键词Binary alloys Calculations Carbides Chromium alloys Chromium compounds Crystal orientation Deformation Interface states Microstructure Phase interfaces Phase transitions Single crystals Superalloys Catalytic mechanisms Crystal planes Diamond grits First principle calculations Geometric optimization Interface mi-crostructure Interface microstructures Interface reactions Phases transformation Solid-state
ISSN号0169-4332
DOI10.1016/j.apsusc.2022.153531
英文摘要In this work, the solid-state (S/S) interface reaction between single-crystal synthetic diamond grits and binary Ni-Cr alloys has been comprehensively studied on (1 0 0) and (1 1 1) crystal planes using Raman spectroscopy, SEM, TEM, and XPS techniques, in combination with first-principles calculation. The early-stage interfacial chromium carbides formation was found to be dependent on crystal orientation of synthetic diamond, which can be explained by geometric optimization that explores the underlying catalytic mechanisms of Ni-Cr alloys on the relaxation and bonds construction of C atoms on (1 0 0) and (1 1 1) crystal planes of diamond. More importantly, a unique interfacial microstructure, namely a Ni-rich layer instead of interfacial carbides was formed directly on diamond surface of S/S reaction samples at 700 and 900 °C. In addition, the phase transformation between Ni-rich phase and chromium carbides formed in the S/S interface reaction between Ni-Cr alloy and synthetic diamond were comparatively examined at 700 and 900 °C and investigated through a careful TEM lattice mismatches analysis. Ultimately, a mechanism to tailor the S/S interface microstructure by simply designing alloy compositions and reaction temperatures was proposed with experimental validation. © 2022 Elsevier B.V.
WOS研究方向Chemistry ; Materials Science ; Physics
语种英语
出版者Elsevier B.V.
WOS记录号WOS:000802544100003
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/158501]  
专题材料科学与工程学院
作者单位1.School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou; 730000, China;
2.Institute of Manufacturing Engineering, Huaqiao University, Xiamen; 361021, China;
3.School of Mechanical and Mining Engineering, The University of Queensland, Brisbane; QLD; 4072, Australia
推荐引用方式
GB/T 7714
Cheng, Wei,Liu, Zhuo,Lin, Qiaoli,et al. Towards tailorable interface microstructure through Solid-state interface reaction between synthetic diamond grits and sputtered Ni-Cr binary alloy[J]. Applied Surface Science,2022,596.
APA Cheng, Wei.,Liu, Zhuo.,Lin, Qiaoli.,Huang, Guoqin.,Xu, Xipeng.,...&Mu, Dekui.(2022).Towards tailorable interface microstructure through Solid-state interface reaction between synthetic diamond grits and sputtered Ni-Cr binary alloy.Applied Surface Science,596.
MLA Cheng, Wei,et al."Towards tailorable interface microstructure through Solid-state interface reaction between synthetic diamond grits and sputtered Ni-Cr binary alloy".Applied Surface Science 596(2022).
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