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Effect of variable conditions on the adsorption selectivity of molecularly imprinted polymers
Li, Ke2,3; Chen, Zhenbin2,3; Liu, Dong Lei2,3; Zhang, Xin Yu2,3; Ruso, Juan M.4; Tang, Zhenghua1,5; Liu, Zhen6
刊名ADVANCED COMPOSITES AND HYBRID MATERIALS
2018-12-01
卷号1期号:4页码:777-784
关键词Qu-MIP Separation performance Quantitative analysis Variable conditions
ISSN号2522-0128
DOI10.1007/s42114-018-0064-z
英文摘要This work mainly studied the separation performance of quercetin molecularly imprinted polymer (Qu-MIP) on quercetin (Qu) in the presence of other flavonoids which possessed similar structures partially at least under different variable conditions. Results documented that Qu-MIP exhibited a special selectivity to Qu in all conditions, and the special selectivity would be enlarged obviously when the total concentration and temperature increased. Besides, quantitative analysis of the degree of separation (D) and concentration (C) (or temperature (T)) displayed a well linear relationship between lnD and C (or T), and the intercept of line, which we defined as the Napierian logarithm of eigen separation degree, increased with the increase of molecular size, which meant MIP could separation target compounds from complex solution system well if impurities with similar contracture but larger molecular size; D increased with the increase of concentration and temperature, but the slope showed an inverse variation trend with the size of Xn. Slope almost showed an increase trend with the increase of Xn molecule size. With the elevation of temperature, slope presented a decline trend with the increase of Xn molecule size. Based on the basic principal of physical and chemical, related reasons were analyzed in detail.
WOS研究方向Science & Technology - Other Topics ; Materials Science
语种英语
出版者SPRINGERNATURE
WOS记录号WOS:000625481700012
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/155368]  
专题材料科学与工程学院
作者单位1.South China Univ Technol, Guangdong Prov Key Lab Atmospher Environm & Pollu, Guangdong Prov Engn & Technol Res Ctr Environm Ri, Sch Environm & Energy,Guangzhou Higher Educ Mega, Guangzhou 510006, Peoples R China;
2.Lanzhou Univ Technol, State Key Lab Gansu Adv Nonferrous Met Mat, Lanzhou 730050, Gansu, Peoples R China;
3.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China;
4.Univ Santiago de Compostela, Soft Matter & Mol Biophys Grp, Dept Appl Phys, Santiago De Compostela 15782, Spain;
5.South China Univ Technol, Guangzhou Key Lab Surface Chem Energy Mat, New Energy Res Inst, Sch Environm & Energy,Guangzhou Higher Educ Mega, Guangzhou 510006, Peoples R China;
6.Frostburg State Univ, Dept Phys & Engn, Frostburg, MD 21532 USA
推荐引用方式
GB/T 7714
Li, Ke,Chen, Zhenbin,Liu, Dong Lei,et al. Effect of variable conditions on the adsorption selectivity of molecularly imprinted polymers[J]. ADVANCED COMPOSITES AND HYBRID MATERIALS,2018,1(4):777-784.
APA Li, Ke.,Chen, Zhenbin.,Liu, Dong Lei.,Zhang, Xin Yu.,Ruso, Juan M..,...&Liu, Zhen.(2018).Effect of variable conditions on the adsorption selectivity of molecularly imprinted polymers.ADVANCED COMPOSITES AND HYBRID MATERIALS,1(4),777-784.
MLA Li, Ke,et al."Effect of variable conditions on the adsorption selectivity of molecularly imprinted polymers".ADVANCED COMPOSITES AND HYBRID MATERIALS 1.4(2018):777-784.
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