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One-Step Synthesis of N, S Co-doped Porous Carbon Use Ionic Liquid As Dopant for Lithium–Sulfur Batteries
Zhao, Guixiang1; Meng, Yanshuang1,2; Zhang, Hongshuai1; Duan, Mingtao1; Zhu, Fuliang1,2
刊名Journal of Electronic Materials
2021-11-01
卷号50期号:11页码:6237-6244
关键词Carbon Electrodes Ionic liquids Lithium Polysulfides Porous materials Sound insulating materials Sulfur Composite electrode Cycle stability Good stability High specific surface area Host materials One step synthesis Specific capacities Template methods
ISSN号03615235
DOI10.1007/s11664-021-09160-8
英文摘要The development of lithium–sulfur batteries is limited due to its notorious "shuttle effect". Heteroatoms are introduced to the host materials to absorb the polysulfides and further to alleviate the shuttle effect. Herein, porous carbon (NSPC) was successfully prepared by template method and used as sulfur host material. The results show that NSPC has a high specific surface area (697.19 m2 g−1) and abundant heteroatom doping, which helps to enhance the capture and absorption of polysulfides. The prepared S@NSPC was loaded with 76% sulfur, and the composite electrode displayed excellent cycle stability because of its strong polysulfide absorption. The S@NSPC composite electrode shows high initial specific capacity of 741.8 mAh g−1 at 167.5 mA g−1, the capacity of the S@NSPC composite electrode remained 609.8 mAh g−1 after 500 cycles, and the attenuation per cycle was only 0.027%, showing good stability. © 2021, The Minerals, Metals & Materials Society.
WOS研究方向Engineering ; Materials Science ; Physics
语种英语
出版者Springer
WOS记录号WOS:000687002300001
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/150912]  
专题材料科学与工程学院
作者单位1.School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou; 730050, China;
2.State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou; 730050, China
推荐引用方式
GB/T 7714
Zhao, Guixiang,Meng, Yanshuang,Zhang, Hongshuai,et al. One-Step Synthesis of N, S Co-doped Porous Carbon Use Ionic Liquid As Dopant for Lithium–Sulfur Batteries[J]. Journal of Electronic Materials,2021,50(11):6237-6244.
APA Zhao, Guixiang,Meng, Yanshuang,Zhang, Hongshuai,Duan, Mingtao,&Zhu, Fuliang.(2021).One-Step Synthesis of N, S Co-doped Porous Carbon Use Ionic Liquid As Dopant for Lithium–Sulfur Batteries.Journal of Electronic Materials,50(11),6237-6244.
MLA Zhao, Guixiang,et al."One-Step Synthesis of N, S Co-doped Porous Carbon Use Ionic Liquid As Dopant for Lithium–Sulfur Batteries".Journal of Electronic Materials 50.11(2021):6237-6244.
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