Cleverly embedded CoS2/NiS2 on two-dimensional graphene nanosheets as high-performance anode material for improved sodium ion batteries and sodium ion capacitors | |
Liu, Jian1; Xu, Ying-Ge1; Kong, Ling-Bin1,2 | |
刊名 | Journal of Materials Science: Materials in Electronics |
2020-06-01 | |
卷号 | 31期号:12页码:9946-9959 |
关键词 | Anodes Electric conductivity Lithium-ion batteries Metal ions Nickel compounds Particle size Sulfur compounds Virtual storage Electrical conductivity Electrochemical performance Graphene nanosheets High reversible capacities High-performance anode materials Hydrothermal process Large specific surface areas Synergistic effect |
ISSN号 | 09574522 |
DOI | 10.1007/s10854-020-03541-1 |
英文摘要 | The CoS2/NiS2-RGO composite with excellent electrochemical performance is first used as an anode material for sodium-ion capacitors (SICs) and sodium-ion batteries (SIBs). CoS2/NiS2-RGO is prepared by one-step hydrothermal process. In half-cell tests, CoS2/NiS2-RGO exhibits a remarkably high reversible capacity of 473.7 mA h g−1 after 50 cycles at the specific current of 100 mA g−1. SICs show an impressive energy density of 139.1 W h kg−1 at the power density of 14,000 W kg−1, which has great advantages compare to the commercial lithium ion batteries. SIBs also show a good capacity of 50 mA h g−1 at a rate of 5 °C. The excellent electrochemical performance of CoS2/NiS2-RGO is mainly attributed to the heterostructure formed by CoS2 and NiS2, which effectively improves the electrical conductivity. On the other hand, there is a good synergistic effect between RGO and CoS2/NiS2. The large specific surface area of RGO makes CoS2/NiS2 disperse uniformly on the surface of RGO, preventing agglomeration and reducing particle size of CoS2/NiS2. In turn, CoS2/NiS2 acting on the surface layer of RGO hinders the secondary overlap and increases the electrical conductivity of RGO. The mixed bimetallic sulfide/RGO system is expected to promote the rapid development of sodium storage devices. © 2020, Springer Science+Business Media, LLC, part of Springer Nature. |
WOS研究方向 | Engineering ; Materials Science ; Physics |
语种 | 英语 |
出版者 | Springer |
WOS记录号 | WOS:000532114500002 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/115059] |
专题 | 石油化工学院 材料科学与工程学院 |
作者单位 | 1.State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals, Lanzhou University of Technology, Lanzhou; 730050, China; 2.School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou; 730050, China |
推荐引用方式 GB/T 7714 | Liu, Jian,Xu, Ying-Ge,Kong, Ling-Bin. Cleverly embedded CoS2/NiS2 on two-dimensional graphene nanosheets as high-performance anode material for improved sodium ion batteries and sodium ion capacitors[J]. Journal of Materials Science: Materials in Electronics,2020,31(12):9946-9959. |
APA | Liu, Jian,Xu, Ying-Ge,&Kong, Ling-Bin.(2020).Cleverly embedded CoS2/NiS2 on two-dimensional graphene nanosheets as high-performance anode material for improved sodium ion batteries and sodium ion capacitors.Journal of Materials Science: Materials in Electronics,31(12),9946-9959. |
MLA | Liu, Jian,et al."Cleverly embedded CoS2/NiS2 on two-dimensional graphene nanosheets as high-performance anode material for improved sodium ion batteries and sodium ion capacitors".Journal of Materials Science: Materials in Electronics 31.12(2020):9946-9959. |
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