Three-Dimensional Interconnected Microporous Carbon Network Derived from Aniline Formaldehyde Resin/Sodium Polyacrylate Interpenetrating Polymer Networks (AF/PAAS IPNs) with Controllable Porosity for Supercapacitors

doi:10.1021/acsaem.9b01044

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	Three-Dimensional Interconnected Microporous Carbon Network Derived from Aniline Formaldehyde Resin/Sodium Polyacrylate Interpenetrating Polymer Networks (AF/PAAS IPNs) with Controllable Porosity for Supercapacitors
	Ma, Yan-Dong 1; Chen, Xi-Wen 1; Kong, Ling-Bin 1,2
刊名	ACS APPLIED ENERGY MATERIALS
	2019-09
卷号	2 期号:9 页码:6440-6452
关键词	interpenetrating polymer networks microporous carbon controllable pore size supercapacitors electrochemical performance
ISSN号	2574-0962
DOI	10.1021/acsaem.9b01044
英文摘要	A facile strategy for the synthesis of three-dimensional nitrogen-doped microporous carbon (MC-IPNx) is reported here. We adopt the advantages of cross-linking individually of interpenetrating polymer networks to synthesize porous carbon with well-controlled micropores (similar to 0.6 nm) and interconnected pores by one-step carbonization of aniline formaldehyde resin/sodium polyacrylate interpenetrating polymer networks (AF/PAAS IPNs), a radically different approach that allows AF/PAAS IPNs to be directly converted to nitrogen-doped microporous carbon (MC-IPNx) without any pretreatment. Due to the interpenetrating pores and abundant porosity, MC-IPNx acquired a high specific surface area (1275 m(2) g(-1)), which reveals remarkable specific capacity (223 F g(-1) at a current density of 1 A g(-1)) and superb capacity retention (80% retention in a current density within the range 0.5-10 A g(-1)). The unique pore structure of MC-IPNx provides an innovative idea for the control of pore size, and advanced electrochemical performance indicates its application prospects.
资助项目	National Natural Science Foundation of China[51762031] ; Foundation for Innovation Groups of Basic Research in Gansu Province[1606RJIA322]
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000487770000038
状态	已发表
内容类型	期刊论文
源URL	[http://ir.lut.edu.cn/handle/2XXMBERH/64272]
专题	省部共建有色金属先进加工与再利用国家重点实验室材料科学与工程学院
通讯作者	Kong, Ling-Bin
作者单位	1.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China 2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式 GB/T 7714	Ma, Yan-Dong,Chen, Xi-Wen,Kong, Ling-Bin. Three-Dimensional Interconnected Microporous Carbon Network Derived from Aniline Formaldehyde Resin/Sodium Polyacrylate Interpenetrating Polymer Networks (AF/PAAS IPNs) with Controllable Porosity for Supercapacitors[J]. ACS APPLIED ENERGY MATERIALS,2019,2(9):6440-6452.
APA	Ma, Yan-Dong,Chen, Xi-Wen,&Kong, Ling-Bin.(2019).Three-Dimensional Interconnected Microporous Carbon Network Derived from Aniline Formaldehyde Resin/Sodium Polyacrylate Interpenetrating Polymer Networks (AF/PAAS IPNs) with Controllable Porosity for Supercapacitors.ACS APPLIED ENERGY MATERIALS,2(9),6440-6452.
MLA	Ma, Yan-Dong,et al."Three-Dimensional Interconnected Microporous Carbon Network Derived from Aniline Formaldehyde Resin/Sodium Polyacrylate Interpenetrating Polymer Networks (AF/PAAS IPNs) with Controllable Porosity for Supercapacitors".ACS APPLIED ENERGY MATERIALS 2.9(2019):6440-6452.