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PtSn nanoparticles supported on iron nanoparticles wrapped inside nitrogen-doped carbon for ethanol oxidation
Wang, Hui; Zhao, Qiuping; Ma, Qin
刊名IONICS
2015-06
卷号21期号:6页码:1703-1709
关键词Nitrogen-doped carbon Support Platinum-based catalyst Ethanol oxidation Fuel cell
ISSN号0947-7047
DOI10.1007/s11581-014-1326-6
英文摘要Iron nanoparticles wrapped in N-doped carbon (INC) were synthesized by a two-step method which includes a hydrothermal and a thermal treatment. The PtSn nanoparticles were then deposited on the resulting carbon material using an ethylene glycol reduction method. Scanning electron microscopy images indicated INC had an interconnected, porous framework with continuous macropores in the micrometer range. Transmission electronic microscopy and X-ray diffraction results proved that the iron nanoparticles were completely wrapped in the N-doped carbon. Cyclic voltammograms for ethanol oxidation showed that the mass activity on PtSn/INC electrode reaches 424.5 mA mg(-1) (Pt), 1.64 times as large as that for PtSn/C (259.0 mA mg(-1) (Pt)). PtSn/INC also exhibited better durability in ethanol oxidation reaction than PtSn/C. These results indicated that INC is a potential high-performance catalyst support material for fuel cell catalysts.
资助项目National Natural Science Foundation of China[51362027]
WOS研究方向Chemistry ; Electrochemistry ; Physics
语种英语
出版者SPRINGER HEIDELBERG
WOS记录号WOS:000354714900023
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/34036]  
专题石油化工学院
材料科学与工程学院
通讯作者Ma, Qin
作者单位Lanzhou Univ Technol, Coll Mat Sci & Engn, Lanzhou 730050, Peoples R China
推荐引用方式
GB/T 7714
Wang, Hui,Zhao, Qiuping,Ma, Qin. PtSn nanoparticles supported on iron nanoparticles wrapped inside nitrogen-doped carbon for ethanol oxidation[J]. IONICS,2015,21(6):1703-1709.
APA Wang, Hui,Zhao, Qiuping,&Ma, Qin.(2015).PtSn nanoparticles supported on iron nanoparticles wrapped inside nitrogen-doped carbon for ethanol oxidation.IONICS,21(6),1703-1709.
MLA Wang, Hui,et al."PtSn nanoparticles supported on iron nanoparticles wrapped inside nitrogen-doped carbon for ethanol oxidation".IONICS 21.6(2015):1703-1709.
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