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Isothermal nanocrystallization behavior of bulk metallic glass composites in supercooled liquid region
Zhang, Xiang-Yun; Yuan, Zi-Zhou; Feng, Xue-Lei; Cui, Li-Zhi; Li, Duan-Xian
刊名RARE METALS
2017-11
卷号36期号:11页码:919-924
关键词Composite Bulk metallic glasses Thermal stability Heat treatment Crystallization
ISSN号1001-0521
DOI10.1007/s12598-014-0358-4
英文摘要Bulk metallic glass composites (BMGCs) reinforced by micro- (spherical size of about 10 mu m) and nano-sized (20-50 nm) Al3Zr crystals were synthesized by copper mold suction casting method. The isothermal crystallization of Cu40Zr44Ag8Al8 BMGCs in the supercooled liquid region was studied by differential scanning calorimeter (DSC), X-ray diffractometer (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The mechanisms for nucleation and growth of the crystalline phases precipitated in two-stage crystallization process and the effect of the isothermal treatment on the in situ crystalline phases were discussed. Results show that the BMGCs experience a primary crystallization process. Nano-sized Al3Zr and Cu10Zr7 phases precipitate from the amorphous matrix successively. Furthermore, isothermal annealing has no effect on the pre-existing particles in the as-cast sample, which creates a new method to synthesize BMGCs strengthened by duplex crystalline phases with a large size difference. And the reinforced phase could also be dominated with intention if the as-cast BMGCs preparation and isothermal treatment process can be controlled more accurately.
资助项目National Natural Science Foundation of China[51061008][50961008]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
出版者NONFERROUS METALS SOC CHINA
WOS记录号WOS:000413105500011
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/33030]  
专题材料科学与工程学院
通讯作者Yuan, Zi-Zhou
作者单位Lanzhou Univ Technol, State Key Lab Adv Nonferrous Mat, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Xiang-Yun,Yuan, Zi-Zhou,Feng, Xue-Lei,et al. Isothermal nanocrystallization behavior of bulk metallic glass composites in supercooled liquid region[J]. RARE METALS,2017,36(11):919-924.
APA Zhang, Xiang-Yun,Yuan, Zi-Zhou,Feng, Xue-Lei,Cui, Li-Zhi,&Li, Duan-Xian.(2017).Isothermal nanocrystallization behavior of bulk metallic glass composites in supercooled liquid region.RARE METALS,36(11),919-924.
MLA Zhang, Xiang-Yun,et al."Isothermal nanocrystallization behavior of bulk metallic glass composites in supercooled liquid region".RARE METALS 36.11(2017):919-924.
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