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Thermo-responsive polysulfone membranes with good anti-fouling property modified by grafting random copolymers via surface-initiated eATRP
Li, Dan2; Niu, Xiaoqin3; Yang, Shiyuan4; Chen, Yuhong3; Ran, Fen1,2
刊名SEPARATION AND PURIFICATION TECHNOLOGY
2018-11-29
卷号206页码:166-176
关键词Thermo-responsive Polyethersulfone Anti-fouling Membrane ATRP
ISSN号1383-5866
DOI10.1016/j.seppur.2018.05.046
英文摘要We graft thermo-responsive polymer chains of PNIPAm, random polymer chains of P(NIPAm-co-Am), and P (NIPAm-co-GMA) on the surface of polyethersophone membrane via SI-eATRP method. The polymer chains of PNIPAm are thermo-responsive segment, and PAm and PGMA are hydrophilic and hydrophobic segment, respectively, which endow the modified membrane thermo-responsive property and adjust the lower critical solution temperature (LCST) of the modified membrane. The influence of temperature on membrane permeation and fouling process are investigated. The LCST is determined by filtration experiment at different temperature. The results show that all modified membranes have thereto-responsive behavior, and LCST of M-PNIPAm-co-PAm increased to 38 degrees C compared with M-PNIPAm; but M-PNIPAm-co-PGMA has the same LCST with M-PNIPAm. The modified membranes have higher flux than that of pristine polyethersulphone membrane whether feeding with pure water or BSA solution, which mainly owing to the hydrophilic surface and rich porosity of modified membranes.
资助项目State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals[18LHPY002]
WOS研究方向Engineering
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000445719000017
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/32326]  
专题理学院
材料科学与工程学院
石油化工学院
省部共建有色金属先进加工与再利用国家重点实验室
通讯作者Ran, Fen
作者单位1.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China
2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China
3.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Gansu, Peoples R China
4.PetroChina Co Ltd, Lanzhou Chem Res Ctr, Lanzhou 730060, Gansu, Peoples R China
推荐引用方式
GB/T 7714
Li, Dan,Niu, Xiaoqin,Yang, Shiyuan,et al. Thermo-responsive polysulfone membranes with good anti-fouling property modified by grafting random copolymers via surface-initiated eATRP[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2018,206:166-176.
APA Li, Dan,Niu, Xiaoqin,Yang, Shiyuan,Chen, Yuhong,&Ran, Fen.(2018).Thermo-responsive polysulfone membranes with good anti-fouling property modified by grafting random copolymers via surface-initiated eATRP.SEPARATION AND PURIFICATION TECHNOLOGY,206,166-176.
MLA Li, Dan,et al."Thermo-responsive polysulfone membranes with good anti-fouling property modified by grafting random copolymers via surface-initiated eATRP".SEPARATION AND PURIFICATION TECHNOLOGY 206(2018):166-176.
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