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A low-cost "water-in-salt" electrolyte for a 2.3 V high-rate carbon-based supercapacitor
Bu, Xudong1,4; Su, Lijun1,2; Dou, Qingyun1,2; Lei, Shulai1; Yan, Xingbin1,2,3
刊名JOURNAL OF MATERIALS CHEMISTRY A
2019-04-07
卷号7期号:13页码:7541-7547
关键词Carbon Costs Electrolytes Inorganic compounds Sodium compounds Supercapacitor
ISSN号2050-7488
DOI10.1039/c9ta00154a
英文摘要Aqueous electrolytes have shown extraordinary promise for safe electrochemical energy storage devices, but their widespread use is severely limited by the narrow electrochemical stability window (ESW). Here we demonstrate the great feasibility of using a superconcentrated sodium perchlorate aqueous solution as a low-cost water-in-salt electrolyte to construct a high-performance carbon-based supercapacitor (SC). The attractive features of this electrolyte including wide ESW and excellent conductivity enable the model SC to fully work at 2.3 volts with superior rate capability and outstanding cycling stability. This SC exhibits a comparable energy density, a higher power density and a much lower price compared to commercial non-aqueous SCs working at 2.7 volts, representing significant progress toward practical applications.
资助项目National Natural Science Foundation of China[21573265] ; National Natural Science Foundation of China[21673263]
WOS研究方向Chemistry ; Energy & Fuels ; Materials Science
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000463819400023
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/31960]  
专题材料科学与工程学院
通讯作者Yan, Xingbin
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lab Clean Energy Chem & Mat, Lanzhou 730000, Gansu, Peoples R China
2.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100039, Peoples R China
3.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
4.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式
GB/T 7714
Bu, Xudong,Su, Lijun,Dou, Qingyun,et al. A low-cost "water-in-salt" electrolyte for a 2.3 V high-rate carbon-based supercapacitor[J]. JOURNAL OF MATERIALS CHEMISTRY A,2019,7(13):7541-7547.
APA Bu, Xudong,Su, Lijun,Dou, Qingyun,Lei, Shulai,&Yan, Xingbin.(2019).A low-cost "water-in-salt" electrolyte for a 2.3 V high-rate carbon-based supercapacitor.JOURNAL OF MATERIALS CHEMISTRY A,7(13),7541-7547.
MLA Bu, Xudong,et al."A low-cost "water-in-salt" electrolyte for a 2.3 V high-rate carbon-based supercapacitor".JOURNAL OF MATERIALS CHEMISTRY A 7.13(2019):7541-7547.
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