synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties
	Li Hongyi; Zhao Yi; Pan Shilie; Wu Hongping; Yu Hongwei; Zhang Fangfang; Yang Zhihua; Poeppelmeier Kenneth R.
刊名	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
	2013
期号	18 页码:3185-3190
关键词	Borates Phosphates Lead Nonlinear optics
ISSN号	1434-1948
通讯作者	Pan, SL
中文摘要	For the first time, single crystals of KPbBP2O8 with sizes up to 18x13x6 mm have been grown from a stoichiometric mixture of its components by the top seed growth method. The crystal structure was determined from single-crystal X-ray data: tetragonal, space group I$\bar {4}$2d, a = 7.1464(7) angstrom, c = 13.8917(16) angstrom, Z = 4. It exhibits an isolated [BP2O8]3- unit that is built from nearly ideal tetrahedral BO4 and PO4 groups, which are connected to each other alternatively by corner-sharing O atoms to make a 12-membered ring. Transmission spectroscopy illustrates that the UV cutoff edge is at approximately 235 nm. Furthermore, IR spectroscopy, thermal analysis, and second-harmonic generation (SHG) measurements were also performed on the reported material.
学科主题	Chemistry
收录类别	SCI
资助信息	973 Program of China 2012CB626803; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of CAS KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of CAS; Funds for Creative Cross & Cooperation Teams of CAS; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research & Development Program of Xinjiang Uygur Autonomous Region of China 201116143; Science and Technology Project of Urumqi G121130002; National Science Foundation Solid State Chemistry Award DMR-1005827
公开日期	2013-11-07
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/2655]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
推荐引用方式 GB/T 7714	Li Hongyi,Zhao Yi,Pan Shilie,et al. synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013(18):3185-3190.
APA	Li Hongyi.,Zhao Yi.,Pan Shilie.,Wu Hongping.,Yu Hongwei.,...&Poeppelmeier Kenneth R..(2013).synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(18),3185-3190.
MLA	Li Hongyi,et al."synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .18(2013):3185-3190.