Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)
	Dong Lingyun; Pan Shilie; Wu Hongping; Su Xin; Yu Hongwei; Wang Ying; Chen Zhaohui; Huang Zhenjun; Yang Zhihua
刊名	JOURNAL OF SOLID STATE CHEMISTRY
	2013
卷号	204 期号:8 页码:64-69
关键词	Pb6B3O10X (X=F, Cl, Br) Oxyborates Crystal structures Syntheses Optical properties
ISSN号	0022-4596
通讯作者	Pan, SL
英文摘要	A series of lead-containing halogen oxyborates, Pb6B3O10X (X=F, Cl, Br), have been grown by high-temperature solution method and their crystal structures were determined by single-crystal X-ray diffraction. They are isostructural and crystallize in the space group Pbcm of the orthorhombic crystal system. The crystal structures are dominated by one-dimensional (infinity)(Pb4O)(BO3)(3)"Zig-Zag"-chains, while the remaining Pb atoms and X (X=F, Cl, Br) atoms are filled to balance the charge. Compared with the previously reported compound Pb4O(BO3)(2) (the molecular formula Pb4O(BO3)(2) can be regarded as Pb6B3O10.5) with the space group Aba2, the structures of Pb6B3O10X (X=F, Cl, Br) are completely different from that of Pb4O(BO3)(2). IR spectroscopy, UV vis-NIR diffuse reflectance spectroscopy, thermal analysis, and theoretical calculations were also performed on the reported materials.
学科主题	Chemistry
收录类别	SCI
WOS记录号	WOS:000322932600011
公开日期	2013-11-07
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/2642]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Dong Lingyun,Pan Shilie,Wu Hongping,et al. Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)[J]. JOURNAL OF SOLID STATE CHEMISTRY,2013,204(8):64-69.
APA	Dong Lingyun.,Pan Shilie.,Wu Hongping.,Su Xin.,Yu Hongwei.,...&Yang Zhihua.(2013).Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br).JOURNAL OF SOLID STATE CHEMISTRY,204(8),64-69.
MLA	Dong Lingyun,et al."Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)".JOURNAL OF SOLID STATE CHEMISTRY 204.8(2013):64-69.