synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10
	Zhou Lin; Pan Shilie; Su Xin; Yu Hongwei; Yang Zhihua; Zhang Fangfang; Zhou Zhongxiang; Han Shujuan
刊名	JOURNAL OF MOLECULAR STRUCTURE
	2013
卷号	1040 期号:5 页码:180-183
关键词	LiPb2B5O10 Borate Synthesis Crystal structure
ISSN号	0022-2860
通讯作者	Pan, SL
中文摘要	A novel lithium dilead pentaborate compound, LiPb2B5O10, is synthesized by the high temperature solution method for the first time. It crystallizes in the monoclinic space group P2(1)/m with lattice constants a = 4.4023(10) angstrom, b = 14.037(3) angstrom, c = 6.8846(16) angstrom, beta = 107.408(2)degrees and Z = 2. The structure consists of B5O (10) units, Liat and PbO7 polyhedra. The B5O10 unit is composed of three BO3 triangles and two Bat tetrahedra. The IR spectrum further confirms the presence of both BO3 and BO4 groups. The calculated band gap via ab initio methods is about 3.433 eV, which is consistent with the experimental result obtained from UV-vis-NIR diffuse reflectance spectrum.
学科主题	Chemistry
收录类别	SCI
资助信息	973 Program of China 2012CB626803; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of CAS KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of CAS; Funds for Creative Cross & Cooperation Teams of CAS; Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period 201130111; High Technology Research & Development Program of Xinjiang Uygur Autonomous Region of China 201116143; Science and Technology Project of Urumqi G121130002
公开日期	2013-11-07
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/2658]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhou Lin,Pan Shilie,Su Xin,et al. synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10[J]. JOURNAL OF MOLECULAR STRUCTURE,2013,1040(5):180-183.
APA	Zhou Lin.,Pan Shilie.,Su Xin.,Yu Hongwei.,Yang Zhihua.,...&Han Shujuan.(2013).synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10.JOURNAL OF MOLECULAR STRUCTURE,1040(5),180-183.
MLA	Zhou Lin,et al."synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10".JOURNAL OF MOLECULAR STRUCTURE 1040.5(2013):180-183.