First order speciation of vanadium and chromium in water samples by on-line continuous membrane separation hyphenated to inductively coupled plasma mass spectrometry

	First order speciation of vanadium and chromium in water samples by on-line continuous membrane separation hyphenated to inductively coupled plasma mass spectrometry
	Jia XY ; Gong DR ; Han Y ; Duan TC ; Chen HT
刊名	analytical methods
	2012
卷号	4 期号:2 页码:575-580
关键词	DRC-ICP-MS ATOMIC-ABSORPTION-SPECTROMETRY LIQUID-CHROMATOGRAPHY CELL EXTRACTION CR(VI) CR(III) SURFACE URINE
ISSN号	1759-9660
通讯作者	duan tc
中文摘要	an on-line anion-exchange membrane separation system has been coupled to inductively coupled plasma mass spectrometry (icp-ms) for the total vanadium(v) and chromium (cr) determination and v(iv) and cr(iii) species determination simultaneously. the positive charged v(iv) and cr(iii) species have been efficiently separated from v(v) and cr(vi), and selectively determined by the on-line electrodialyzer-icp-ms. to determine the total concentrations of v and cr in water samples, h2so4 and na2s2o3 were added to convert all vanadium and chromium species into their positive species, thus, v(v) and cr(vi) in the samples were quantified by subtraction. the cool plasma and reaction gas can also be avoided as the severe interference from chloride, carbon and nitrogen-based molecular ion has been substantially suppressed by the anion-exchange membrane. the detection limits of the analytes were 0.02 mu g l-1 for v(iv) and 0.06 mu g l-1 for cr(iii) with this on-line system, respectively, and the relative standard deviation (n = 10) of 10 mu g l-1 v(iv) and cr(iii) were 3.7% and 2.1%, respectively. the developed method has been applied for the speciation of v and cr in three water samples, with v(v) and cr(iii) found as the main species in these samples. the accuracy and feasibility of this method have also been verified by spike tests and a certified reference material (crm) of environmental water (gsbz 50029-94) and a crm of riverine water (gbw 08608), good recoveries have been obtained and the analytical results are also in good agreement with the certified values.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000300038900042
公开日期	2013-10-31
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/48877]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Jia XY,Gong DR,Han Y,et al. First order speciation of vanadium and chromium in water samples by on-line continuous membrane separation hyphenated to inductively coupled plasma mass spectrometry[J]. analytical methods,2012,4(2):575-580.
APA	Jia XY,Gong DR,Han Y,Duan TC,&Chen HT.(2012).First order speciation of vanadium and chromium in water samples by on-line continuous membrane separation hyphenated to inductively coupled plasma mass spectrometry.analytical methods,4(2),575-580.
MLA	Jia XY,et al."First order speciation of vanadium and chromium in water samples by on-line continuous membrane separation hyphenated to inductively coupled plasma mass spectrometry".analytical methods 4.2(2012):575-580.