Solid supported ruthenium catalyst for growing single-walled carbon nanotubes with narrow chirality distribution

doi:10.1016/j.carbon.2022.03.010

CORC > 金属研究所 > 中国科学院金属研究所

	Solid supported ruthenium catalyst for growing single-walled carbon nanotubes with narrow chirality distribution
	Zhang, Xueting 6; Qian, Liu 5; Yao, Xiaojing 3,4; Zhang, Lili 3; Wu, Qianru 6; Li, Dong 6; Ma, Chen 6; Zhao, Nan 6; Xin, Liantao 6; Liu, Chang 3
刊名	CARBON
	2022-06-30
卷号	193 页码:35-41
关键词	Single-walled carbon nanotubes Ruthenium catalyst Selective growth Chemical vapor deposition
ISSN号	0008-6223
DOI	10.1016/j.carbon.2022.03.010
通讯作者	Zhang, Xiuyun(xyzhang@yzu.edu.cn) ; He, Maoshuai(hemaoshuai@qust.edu.cn)
英文摘要	The past two decades witnessed the thriving of non-conventional nanoparticles in catalytic synthesis of single-walled carbon nanotubes (SWNTs). However, most of the SWNTs are limited to growing on a flat surface which usually suffers low output, thus making the evaluation of SWNT chirality distribution challenging. In this work, we report a solid magnesia (MgO) supported ruthenium (Ru) catalyst for chemical vapor deposition (CVD) growth of SWNTs with sufficient quantity for optical characterizations. Both MgO supported atomically dispersed Ru catalyst and Ru nanoparticles pre-deposited onto porous MgO are active for catalytic synthesis of small diameter SWNTs. Particularly, enriched (6, 5) SWNTs are achieved at temperatures higher than 800 & nbsp;C by CO CVD, which is partially attributed to the high activity of Ru clusters. Besides, density functional theory (DFT) calculations reveal that the charge transfer from the MgO support to the Ru clusters promotes the carbon precursor absorption and dissociation, ac-counting for the activation of Ru clusters. This work not only demonstrates the application of atomically dispersed catalyst for CVD growth of SWNTs, but also paves the way for the chirality-selective growth of SWNTs from non-magnetic nanoparticles. (C)& nbsp;2022 Elsevier Ltd. All rights reserved.
资助项目	National Natural Science Foundation of China[51972184] ; Key Basic Research Project of Shandong Province[ZR2019ZD49] ; Taishan Scholar Advantage and Characteristic Discipline Team of Eco Chemical Process and Technology
WOS研究方向	Chemistry ; Materials Science
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000802215800004
资助机构	National Natural Science Foundation of China ; Key Basic Research Project of Shandong Province ; Taishan Scholar Advantage and Characteristic Discipline Team of Eco Chemical Process and Technology
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/174371]
专题	金属研究所_中国科学院金属研究所
通讯作者	Zhang, Xiuyun; He, Maoshuai
作者单位	1.Hebei Normal Univ, Hebei Adv Thin Films Lab, Shijiazhuang 050024, Peoples R China 2.Yangzhou Univ, Coll Phys Sci & Technol, Yangzhou 225002, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 4.Hebei Normal Univ, Coll Phys, Shijiazhuang 050024, Peoples R China 5.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing Sci & Engn Ctr Nanocarbons,Ctr Nanochem, Beijing 100871, Peoples R China 6.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, State Key Lab Ecochem Engn, Taishan Scholar Advantage & Characterist Disciplin, Qingdao 266042, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Xueting,Qian, Liu,Yao, Xiaojing,et al. Solid supported ruthenium catalyst for growing single-walled carbon nanotubes with narrow chirality distribution[J]. CARBON,2022,193:35-41.
APA	Zhang, Xueting.,Qian, Liu.,Yao, Xiaojing.,Zhang, Lili.,Wu, Qianru.,...&He, Maoshuai.(2022).Solid supported ruthenium catalyst for growing single-walled carbon nanotubes with narrow chirality distribution.CARBON,193,35-41.
MLA	Zhang, Xueting,et al."Solid supported ruthenium catalyst for growing single-walled carbon nanotubes with narrow chirality distribution".CARBON 193(2022):35-41.