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Temperature Gradient Induced Orientation Change of Bi Grains in Sn-Bi57-Ag0.7 Solder Joint
Chen, Yinbo1,2; Gao, Zhaoqing3; Liu, Zhi-Quan1,4
刊名ACTA METALLURGICA SINICA-ENGLISH LETTERS
2022-01-06
页码11
关键词Sn-Bi-Ag solder Grain orientation Temperature gradient Aging Ag3Sn
ISSN号1006-7191
DOI10.1007/s40195-021-01357-4
通讯作者Liu, Zhi-Quan(zqliu@siat.ac.cn)
英文摘要Sn-Bi-X solders are widely used in electronic packaging industry. However, thermomigration (TM) behaviors of Sn-Bi-X solder joints and the orientations change of Bi grains under the temperature gradient are rarely reported. In this study, Sn-Bi57-Ag0.7/Cu solder joints were used to conduct a TM test under a temperature gradient of 625 degrees C/cm for 400 h, and an isothermal aging test at 85 degrees C was also conducted for comparison. The microstructural evolution of Sn-Bi-X solder joints after reflow, TM and isothermal aging were analyzed by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electron probe microanalysis (EPMA). The results indicated that the Sn/Bi areal ratio after TM did not change significantly whether at the hot end (from 46.78%/52.12% to 50.90%/48.78%) or at the cold end (from 50.25%/49.64% to 48.71%/51.16%) compared with that of as-reflowed samples due to the insufficient thermal energy. The thickness of intermetallic compound (IMC) after TM at hot end (2.49 mu m) was very close to that of the IMC at cold end (2.52 mu m), which was also close to that of the aged samples. In addition, the preferred orientations of Sn and Bi grains in different Sn-Bi-Ag solder joints resulting from different conditions (reflow, TM and isothermal aging) were characterized by electron backscatter diffraction (EBSD). The obtained results demonstrated that both Sn and Bi grains had no preferred orientation whether after reflow or isothermal aging, while the orientation of Bi grains of the sample after TM changed from random direction to c-axis ([0001] direction) parallel to the heat flow. Ag3Sn could hinder the change of orientation of Bi grains under the temperature gradient, and the corresponding mechanism was also systematically illuminated. This study firstly revealed the orientation change of Bi grains under the temperature gradient, which would have a profound guiding significance for enhancing the reliabilities of Sn-Bi-Ag solder joints.
资助项目National Key R&D Program of China[2017YFB0305700]
WOS研究方向Metallurgy & Metallurgical Engineering
语种英语
出版者CHINESE ACAD SCIENCES, INST METAL RESEARCH
WOS记录号WOS:000739243100002
资助机构National Key R&D Program of China
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/173864]  
专题金属研究所_中国科学院金属研究所
通讯作者Liu, Zhi-Quan
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
3.Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China
4.Chinese Acad Sci, Shenzhen Inst Adv Elect Mat, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China
推荐引用方式
GB/T 7714
Chen, Yinbo,Gao, Zhaoqing,Liu, Zhi-Quan. Temperature Gradient Induced Orientation Change of Bi Grains in Sn-Bi57-Ag0.7 Solder Joint[J]. ACTA METALLURGICA SINICA-ENGLISH LETTERS,2022:11.
APA Chen, Yinbo,Gao, Zhaoqing,&Liu, Zhi-Quan.(2022).Temperature Gradient Induced Orientation Change of Bi Grains in Sn-Bi57-Ag0.7 Solder Joint.ACTA METALLURGICA SINICA-ENGLISH LETTERS,11.
MLA Chen, Yinbo,et al."Temperature Gradient Induced Orientation Change of Bi Grains in Sn-Bi57-Ag0.7 Solder Joint".ACTA METALLURGICA SINICA-ENGLISH LETTERS (2022):11.
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