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Effect of thermally induced B2 phase on the corrosion behavior of an Al0.3CoCrFeNi high entropy alloy
Shi, Z. J.3; Wang, Z. B.1; Wang, X. D.2; Zhang, S.3; Zheng, Y. G.1
刊名JOURNAL OF ALLOYS AND COMPOUNDS
2022-05-15
卷号903页码:11
关键词High entropy alloys Pitting Corrosion Precipitation phase Passive film Electrochemistry
ISSN号0925-8388
DOI10.1016/j.jallcom.2022.163886
通讯作者Wang, Z. B.(zbwang12s@imr.ac.cn) ; Zhang, S.(songzhang.sy@163.com)
英文摘要The corrosion resistance of Al-Co-Cr-Fe-Ni high entropy alloys (HEAs) is probably affected by B2 phases. In this paper, the effect of B2 phases on the corrosion behavior of Al0.3CoCrFeNi HEAs in 3.5 wt% NaCl solution is clarified in this paper by purposely controlling the formation of B2 phases using annealing treatment. The microstructure characterization reveals that the content of (Al, Ni)-rich and Cr-poor B2 phases increases and the electrochemical measurements show that the pitting corrosion resistance is deteriorated as the annealing temperature decreases. Accordingly, the B2 phase is confirmed to be detrimental to the corrosion resistance of Al0.3CoCrFeNi HEAs. It can be attributed to the preferential dissolution of B2 phases causing easier pit initiation, which is evidenced by the corrosion morphology observation and scanning Kelvin probe force microscopy measurements, and to the slower repassivation rate leading to easier pit propagation, as demonstrated by the quantitative analysis of potentiostatic polarization curves. (c) 2022 Elsevier B.V. All rights reserved.
资助项目National Key Research and Development Program of China[2016YFB1100204] ; Science and Technology Commission of Liaoning Province[2018106004] ; Shenyang Science and Technology[19-109-1-03]
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000749782500003
资助机构National Key Research and Development Program of China ; Science and Technology Commission of Liaoning Province ; Shenyang Science and Technology
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/173579]  
专题金属研究所_中国科学院金属研究所
通讯作者Wang, Z. B.; Zhang, S.
作者单位1.Chinese Acad Sci, Inst Met Res, CAS Key Lab Nucl Mat & Safety Assessment, 62 Wencui Rd, Shenyang 110016, Peoples R China
2.Univ Sci & Technol Beijing, Natl Ctr Mat Serv Safety, Beijing 100083, Peoples R China
3.Shenyang Univ Technol, Sch Mat Sci & Engn, 111 Shen Liaoxi Rd, Shenyang 110870, Peoples R China
推荐引用方式
GB/T 7714
Shi, Z. J.,Wang, Z. B.,Wang, X. D.,et al. Effect of thermally induced B2 phase on the corrosion behavior of an Al0.3CoCrFeNi high entropy alloy[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2022,903:11.
APA Shi, Z. J.,Wang, Z. B.,Wang, X. D.,Zhang, S.,&Zheng, Y. G..(2022).Effect of thermally induced B2 phase on the corrosion behavior of an Al0.3CoCrFeNi high entropy alloy.JOURNAL OF ALLOYS AND COMPOUNDS,903,11.
MLA Shi, Z. J.,et al."Effect of thermally induced B2 phase on the corrosion behavior of an Al0.3CoCrFeNi high entropy alloy".JOURNAL OF ALLOYS AND COMPOUNDS 903(2022):11.
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