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Stabilizing CuO photocathode with a Cu3N protection shell
Meng, Xiang-dong1,2; Zhen, Chao1; Liu, Gang1,3; Cheng, Hui-Ming1,2,4
刊名CHINESE JOURNAL OF CATALYSIS
2022-03-01
卷号43期号:3页码:755-760
关键词CuO Cu3N Photocathode Stability Water splitting
ISSN号0253-9837
DOI10.1016/S1872-2067(21)63894-9
通讯作者Zhen, Chao(czhen@imr.ac.cn) ; Liu, Gang(gangliu@imr.ac.cn)
英文摘要CuO, as a promising photocathode material, suffers from severe photocorrosion in photoelectrochemical water splitting applications. Herein, a Cu3N protection shell was used to protect the CuO photocathode for the first time to effectively suppress the photocorrosion of CuO. Consequently, the Cu3N-protected CuO photocathode shows improved stability, retaining 80% of its initial current density in a 20-min test, while only 10% of the initial current density can be retained for the bare photocathode. This work may provide an important strategy for using Cu3N shells to stabilize unstable photocathodes. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
资助项目National Natural Science Foundation of China[51825204] ; National Natural Science Foundation of China[52072377] ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences[QYZDB-SSW-JSC039] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[2020192]
WOS研究方向Chemistry ; Engineering
语种英语
出版者ELSEVIER
WOS记录号WOS:000788414700004
资助机构National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/172734]  
专题金属研究所_中国科学院金属研究所
通讯作者Zhen, Chao; Liu, Gang
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China
4.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen Geim Graphene Ctr, Shenzhen 518055, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Meng, Xiang-dong,Zhen, Chao,Liu, Gang,et al. Stabilizing CuO photocathode with a Cu3N protection shell[J]. CHINESE JOURNAL OF CATALYSIS,2022,43(3):755-760.
APA Meng, Xiang-dong,Zhen, Chao,Liu, Gang,&Cheng, Hui-Ming.(2022).Stabilizing CuO photocathode with a Cu3N protection shell.CHINESE JOURNAL OF CATALYSIS,43(3),755-760.
MLA Meng, Xiang-dong,et al."Stabilizing CuO photocathode with a Cu3N protection shell".CHINESE JOURNAL OF CATALYSIS 43.3(2022):755-760.
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