Ba2B5O8(OH)(2)(NO3)center dot 3H(2)O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate

doi:10.1039/d1dt03660b

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	Ba2B5O8(OH)(2)(NO3)center dot 3H(2)O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate
	Hu, HY (Hu, Huaiyu) [1] , [2]; Huang, JB (Huang, Junben) [1]; Guo, ZY (Guo, Zhiyong) [3]; Zhang, M (Zhang, Min) [1] , [2]; Yang, ZH (Yang, Zhihua) [1] , [2]; Pan, SL (Pan, Shilie) [1] , [2]
刊名	DALTON TRANSACTIONS
	2022
卷号	51 期号:5 页码:1979-1984
ISSN号	1477-9226
DOI	10.1039/d1dt03660b
英文摘要	The first alkaline earth metal borate-nitrate, namely Ba2B5O8(OH)(2)(NO3)center dot 3H(2)O (BBNOH), has been synthesized by the hydrothermal method. BBNOH crystallizes in the space group of P2(1)/c and shows two-dimensional (2D) (2)(infinity)[B5O8(OH)(2)](3-) borate anion layers, and the hydrated barium cations and the [NO3](-) anions are located between the layers. The process of optimizing the structure of Ba2B5O8(OH)(2)OH to BBNOH has been discussed. The first principles calculation has been used to calculate the birefringence of Ba2B5O8(OH)(2)(NO3)center dot 3H(2)O, and the value is 0.033@1064 nm, which is mainly originated from the borate anions and the pi conjugated [NO3](-) anions.
WOS记录号	WOS:000742081100001
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/8385]
专题	新疆理化技术研究所_材料物理与化学研究室
通讯作者	Zhang, M (Zhang, Min) [1] , [2]; Pan, SL (Pan, Shilie) [1] , [2]
作者单位	1.Natl Qual Supervis & Inspect Centerfor Ceram Prod, Xuchang Qual & Tech Supervis Inspect & Testing Ct, West Sect Longxing Rd, Xuchang, Henan, Peoples R China 2.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 3.Chinese Acad Sci, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
推荐引用方式 GB/T 7714	Hu, HY ,Huang, JB ,Guo, ZY ,et al. Ba2B5O8(OH)(2)(NO3)center dot 3H(2)O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate[J]. DALTON TRANSACTIONS,2022,51(5):1979-1984.
APA	Hu, HY ,Huang, JB ,Guo, ZY ,Zhang, M ,Yang, ZH ,&Pan, SL .(2022).Ba2B5O8(OH)(2)(NO3)center dot 3H(2)O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate.DALTON TRANSACTIONS,51(5),1979-1984.
MLA	Hu, HY ,et al."Ba2B5O8(OH)(2)(NO3)center dot 3H(2)O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate".DALTON TRANSACTIONS 51.5(2022):1979-1984.