An antimony(iii) borate with large birefringence exhibiting unwonted [B5O11] fundamental building blocks and dimeric [Sb2O6] clusters

doi:10.1039/d1qi00201e

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	An antimony(iii) borate with large birefringence exhibiting unwonted [B5O11] fundamental building blocks and dimeric [Sb2O6] clusters
	Chen, Z (Chen, Zhen) [1] , [2] , [3]; Zeng, H (Zeng, Hao) [1] , [2]; Han, SJ (Han, Shujuan) [1] , [2] , [3]; Yang, ZH (Yang, Zhihua) [1] , [2] , [3]; Pan, SL (Pan, Shilie) [1] , [2] , [3]
刊名	INORGANIC CHEMISTRY FRONTIERS
	2021
卷号	8 期号:10 页码:2584-2590
ISSN号	2052-1553
DOI	10.1039/d1qi00201e
英文摘要	A new birefringent crystal SbB5O9 has been synthesized by combining pi-conjugated [B3O6] groups and Sb3+ cations with SCALP. It exhibits the unwonted [B5O11] fundamental building block (FBB) and dimeric [Sb2O6] cluster. Remarkably, SbB5O9 exhibits a short UV cutoff edge (below 240 nm) and a large birefringence (Delta n = 0.151 @ 1064 nm) which is even better than that of the well-known commercial birefringent material alpha-BaB2O4 (alpha-BBO) (Delta n = 0.122 @ 532 nm). First-principles calculations show that the birefringence enhancement mainly originates from the highly distorted [Sb2O6] dimer and pi-conjugated B-O anionic groups.
WOS记录号	WOS:000639536300001
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/8173]
专题	新疆理化技术研究所_材料物理与化学研究室
通讯作者	Han, SJ (Han, Shujuan) [1] , [2] , [3]; Pan, SL (Pan, Shilie) [1] , [2] , [3]
作者单位	1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Chinese Acad Sci, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
推荐引用方式 GB/T 7714	Chen, Z ,Zeng, H ,Han, SJ ,et al. An antimony(iii) borate with large birefringence exhibiting unwonted [B5O11] fundamental building blocks and dimeric [Sb2O6] clusters[J]. INORGANIC CHEMISTRY FRONTIERS,2021,8(10):2584-2590.
APA	Chen, Z ,Zeng, H ,Han, SJ ,Yang, ZH ,&Pan, SL .(2021).An antimony(iii) borate with large birefringence exhibiting unwonted [B5O11] fundamental building blocks and dimeric [Sb2O6] clusters.INORGANIC CHEMISTRY FRONTIERS,8(10),2584-2590.
MLA	Chen, Z ,et al."An antimony(iii) borate with large birefringence exhibiting unwonted [B5O11] fundamental building blocks and dimeric [Sb2O6] clusters".INORGANIC CHEMISTRY FRONTIERS 8.10(2021):2584-2590.