High-Efficiency Separation of Aromatic Sulfide from Liquid Hydrocarbon Fuel in Conjugated Porous Organic Framework with Polycarbazole Unit

doi:10.1021/acsami.9b15815

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	High-Efficiency Separation of Aromatic Sulfide from Liquid Hydrocarbon Fuel in Conjugated Porous Organic Framework with Polycarbazole Unit
	C.H.Lin; Z.Cheng; B.Li; T.F.Chen; W.X.Zhang; S.H.Chen
刊名	Acs Applied Materials & Interfaces
	2019
卷号	11 期号:43 页码:40970-40979
关键词	porous organic framework,desulfurization,polycarbazole,conjugated,polymer,competitive adsorption,covalent triazine frameworks,nitrogen-compounds,surface-area,gas-storage,diesel fuel
ISSN号	1944-8244
DOI	10.1021/acsami.9b15815
英文摘要	We synthesized three conjugated polycarbazole porous organic frameworks named o-Cz-POF, m-Cz-POF, and p-Cz-POF for hydrocarbon fuels' adsorptive desulfurization. The carbazole building blocks possessed ortho, meta, and para steric configuration, which resulted in POFs exhibiting adjustable specific surface area and pore structure. Adsorption kinetics experiments and DFT calculations were carried out to understand the competitive adsorption of 3-methylthiophene and octane in the Cz-POF. The instantaneous adsorption rate and adsorption energy calculation analyses gave a convincing demonstration on preferential selective adsorption of 3-methylthiophene in Cz-POFs. Furthermore, the fixed bed breakthrough experiment demonstrated that the Cz-POFs can selectively adsorb 3-methylthiophene efficiently, and hydrocarbon fuel with sulfide content close to 0 ppm was obtained. The features of high stability and high desulfurization efficiency of Cz-POFs make them hold the promise as a new type of porous adsorbent for ultradeep adsorption desulfurization.
URL标识	查看原文
语种	英语
内容类型	期刊论文
源URL	[http://ir.ciomp.ac.cn/handle/181722/63221]
专题	中国科学院长春光学精密机械与物理研究所
推荐引用方式 GB/T 7714	C.H.Lin,Z.Cheng,B.Li,et al. High-Efficiency Separation of Aromatic Sulfide from Liquid Hydrocarbon Fuel in Conjugated Porous Organic Framework with Polycarbazole Unit[J]. Acs Applied Materials & Interfaces,2019,11(43):40970-40979.
APA	C.H.Lin,Z.Cheng,B.Li,T.F.Chen,W.X.Zhang,&S.H.Chen.(2019).High-Efficiency Separation of Aromatic Sulfide from Liquid Hydrocarbon Fuel in Conjugated Porous Organic Framework with Polycarbazole Unit.Acs Applied Materials & Interfaces,11(43),40970-40979.
MLA	C.H.Lin,et al."High-Efficiency Separation of Aromatic Sulfide from Liquid Hydrocarbon Fuel in Conjugated Porous Organic Framework with Polycarbazole Unit".Acs Applied Materials & Interfaces 11.43(2019):40970-40979.