Synthesis, structure and third-order optical nonlinearities of hyperbranched metal phthalocyanines containing imide units

doi:10.1016/j.dyepig.2018.02.031

CORC > 长春光学精密机械与物理研究所 > 中国科学院长春光学精密机械与物理研究所

	Synthesis, structure and third-order optical nonlinearities of hyperbranched metal phthalocyanines containing imide units
	Wang, T. F.; Wang, X.; Zhang, J. L.; Wang, C. R.; Shao, J. F.; Jiang, Z. H.; Zhang, Y. H.
刊名	Dyes and Pigments
	2018
卷号	154 页码:75-81
关键词	Hyperbranched Phthalocyanines Nonlinearities Imide unit Molecular structure excited-state dynamics polyimides complexes polymers beam Chemistry Engineering Materials Science
ISSN号	0143-7208
DOI	10.1016/j.dyepig.2018.02.031
英文摘要	A series of thermally stable and soluble hyperbranched metal phthalocyanines oligomers containing imide units (HMePcIs) ending with carboxyl groups were synthesized successfully. The number of the Pc rings was first estimated by analyzing the terminal carboxyl groups in the H-1 NMR spectra of HMePcIs. The third-order nonlinear optical (NLO) properties of these oligomers were measured by a Z-scan technique with a pulsed Q-switched Nd: YAG laser system at 532 nm. The introduced imide unit noticeably improved the thermal stability and third-order nonlinear susceptibility, chi((3)). The 5 wt% weight loss temperature for HMePcIs exceeded 410 degrees C, and the chi((3)) values reached the order of 10(-13) esu. The variation of the center metals of HMePcIs influenced the third-order optical nonlinearity, and the third-order nonlinear susceptibility chi((3)) values of hyperbranched metal (Zn,Cu, Ni) phthalocyanines oligomers were found to rank in the order of HZnPcI > HCuPcI > HNiPcI.
内容类型	期刊论文
源URL	[http://ir.ciomp.ac.cn/handle/181722/61174]
专题	中国科学院长春光学精密机械与物理研究所
推荐引用方式 GB/T 7714	Wang, T. F.,Wang, X.,Zhang, J. L.,et al. Synthesis, structure and third-order optical nonlinearities of hyperbranched metal phthalocyanines containing imide units[J]. Dyes and Pigments,2018,154:75-81.
APA	Wang, T. F..,Wang, X..,Zhang, J. L..,Wang, C. R..,Shao, J. F..,...&Zhang, Y. H..(2018).Synthesis, structure and third-order optical nonlinearities of hyperbranched metal phthalocyanines containing imide units.Dyes and Pigments,154,75-81.
MLA	Wang, T. F.,et al."Synthesis, structure and third-order optical nonlinearities of hyperbranched metal phthalocyanines containing imide units".Dyes and Pigments 154(2018):75-81.