With the rapid advance of science and technology, it is essential to research and develop new intrinsic solar absorber coatings with the simple production process and excellent photo-thermal conversion efficiency. Herein, we have developed a novel AlCrMoTaTiN intrinsic absorber layer by radio frequency (RF) reactive sputtering method via adjusting the deposition time and the flow rate of N₂. The AlCrMoTaTiN intrinsic absorber layer exhibits a high absorptance of 0.752 and a low emittance of 0.074 at 82 °C. The AlCrMoTaTiN/Al₂O₃ solar absorber coating is deposited by using Al₂O₃ works as an anti-reflective layer and the spectral selectivity (α/ε) is 0.929/0.082. This coating also possesses a good thermal stability, which can be stabilized at 300 °C in air and 500 °C in vacuum for 2 h, respectively. In addition, a prolonged period of thermal stability characterization is carried out, which indicates that this coating could keep good optical performance after annealing at 600 °C for 100 h. The corresponding failure mechanism is obtained by analyzing the Raman spectroscopy and XRD. Obviously, the AlCrMoTaTiN/Al₂O₃ solar absorber coating has a broad application prospect in large-scale and efficient industrial production.