A general strategy to prepare atomically dispersed biomimetic catalysts based on host-guest chemistry | |
Han, Xiao1; Chen, Zheng2,3; Chen, Wenxing2,4; Lv, Chunlin5,6; Ji, Yongjun7,8; Li, Jing8; Cheong, Weng-Chon2; Lei, Xiaojuan1; Peng, Qing2; Chen, Chen2 | |
刊名 | CHEMICAL COMMUNICATIONS |
2021-02-21 | |
卷号 | 57期号:15页码:1895-1898 |
ISSN号 | 1359-7345 |
DOI | 10.1039/d0cc07119f |
英文摘要 | Herein, we report a general strategy based on host-guest interactions to fabricate atomically dispersed biomimetic catalysts, which were evaluated by diboration of phenylacetylene. The structure and function of these mimics are quite similar to those of enzymes, namely, the atomically dispersed metal serves as an active site, the external macromolecular structure plays a role as an enzyme catalytic pocket to stabilize the reaction intermediates and the interactions between the intermediates and functional groups near to the active site can reduce the reaction activation energy. |
资助项目 | National Natural Science Foundation of China[21701007] ; National Natural Science Foundation of China[21801015] |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000620719300009 |
资助机构 | National Natural Science Foundation of China |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/47887] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Lian, Chao |
作者单位 | 1.Beijing Jiaotong Univ, Sch Sci, Dept Chem, Beijing 100044, Peoples R China 2.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 3.Anhui Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Mol Solids, Anhui Key Lab Mol Based Mat,Minist Educ, Wuhu 241000, Peoples R China 4.Being Inst Technol, Beijing Key Lab Construct Tailorable Adv Funct Ma, Sch Mat Sci & Engn, Beijing 100081, Peoples R China 5.Minzu Univ China, Sch Pharm, Beijing 100081, Peoples R China 6.Minzu Univ China, Ctr Translat Neurosci, Beijing 100081, Peoples R China 7.Beijing Technol & Business Univ, Sch Light Ind, Beijing 100048, Peoples R China 8.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China 9.Beijing Single Atom Site Catalysis Technol Co Ltd, Beijing 100094, Peoples R China |
推荐引用方式 GB/T 7714 | Han, Xiao,Chen, Zheng,Chen, Wenxing,et al. A general strategy to prepare atomically dispersed biomimetic catalysts based on host-guest chemistry[J]. CHEMICAL COMMUNICATIONS,2021,57(15):1895-1898. |
APA | Han, Xiao.,Chen, Zheng.,Chen, Wenxing.,Lv, Chunlin.,Ji, Yongjun.,...&Li, Yadong.(2021).A general strategy to prepare atomically dispersed biomimetic catalysts based on host-guest chemistry.CHEMICAL COMMUNICATIONS,57(15),1895-1898. |
MLA | Han, Xiao,et al."A general strategy to prepare atomically dispersed biomimetic catalysts based on host-guest chemistry".CHEMICAL COMMUNICATIONS 57.15(2021):1895-1898. |
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