Synthesis of Porous and Highly Crystallinity Vanadium Phosphorus Oxide Catalysts by Multifunctional Biomass-Based Deep Eutectic Solvents

doi:10.1021/acs.jpcb.0c01564

	Synthesis of Porous and Highly Crystallinity Vanadium Phosphorus Oxide Catalysts by Multifunctional Biomass-Based Deep Eutectic Solvents
	He, Bin 1,2; Li, Yingwei 1,2; Zhang, Ting 1; Shi, Yanan 1; Li, Kang 1; Dai, Fei 1; Zhang, Ruirui 1; Liu, Ruixia 1,2; Zhang, Suojiang 1,2
刊名	JOURNAL OF PHYSICAL CHEMISTRY B
	2020-05-07
卷号	124 期号:18 页码:3743-3753
ISSN号	1520-6106
DOI	10.1021/acs.jpcb.0c01564
英文摘要	Deep eutectic solvents (DESs) as a novel class of ionic liquid analogues has been widely used in various fields. Herein, a multifunctional biomass-based DES composed of choline chloride (ChCl) and glucose (GLU) was synthesized and used for the modification of vanadium phosphorus oxide (VPO) catalyst, which is the sole catalyst for the selective oxidation of n-butane to maleic anhydride (MA) in industry. The DES is more green, cost-effective and efficient compared with traditional modifier (metal inorganics and organic polymers). A combination of structure and catalytic performance was investigated in detail to deeply understand its functions. Initially, this DES plays the role of structure directing agent at the stage of precursor synthesis, which can induce the formation of active plane and obtain highly crystalline precursors. Accordingly, the active phase with highly crystalline was obtained after the activation of precursors. Additionally, the DES was decomposed during the precursors activation, resulting in the formation of porous structure around 20 nm on the active plane. Besides this, the surface chemical state including the valence state and acid-base property was changed significantly due to the function of DES. All of these lead to about an 11% increase of MA mass yield, which has great significance to the high value utilization of low carbon alkanes.
资助项目	National Key Research and Development Program of China[2017YFA0206803] ; National Nature Science Foundation of China[21808223] ; Key Programs of the Chinese Academy of Sciences[KFZD-SW-413] ; Key Programs of Fujian Institute of Innovation, CAS[FJCXY18020203] ; K. C. Wong Education Foundation[GJTD-2018-04]
WOS关键词	N-BUTANE OXIDATION ; MIXED-METAL OXIDES ; SELECTIVE OXIDATION ; MALEIC-ANHYDRIDE ; VPO CATALYSTS ; IONIC LIQUIDS ; PYROPHOSPHATE CATALYST ; EXFOLIATION-REDUCTION ; PHOSPHATE CATALYSTS ; ASSISTED SYNTHESIS
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000549966700017
资助机构	National Key Research and Development Program of China ; National Nature Science Foundation of China ; Key Programs of the Chinese Academy of Sciences ; Key Programs of Fujian Institute of Innovation, CAS ; K. C. Wong Education Foundation
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/41443]
专题	中国科学院过程工程研究所
通讯作者	Liu, Ruixia; Zhang, Suojiang
作者单位	1.Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	He, Bin,Li, Yingwei,Zhang, Ting,et al. Synthesis of Porous and Highly Crystallinity Vanadium Phosphorus Oxide Catalysts by Multifunctional Biomass-Based Deep Eutectic Solvents[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2020,124(18):3743-3753.
APA	He, Bin.,Li, Yingwei.,Zhang, Ting.,Shi, Yanan.,Li, Kang.,...&Zhang, Suojiang.(2020).Synthesis of Porous and Highly Crystallinity Vanadium Phosphorus Oxide Catalysts by Multifunctional Biomass-Based Deep Eutectic Solvents.JOURNAL OF PHYSICAL CHEMISTRY B,124(18),3743-3753.
MLA	He, Bin,et al."Synthesis of Porous and Highly Crystallinity Vanadium Phosphorus Oxide Catalysts by Multifunctional Biomass-Based Deep Eutectic Solvents".JOURNAL OF PHYSICAL CHEMISTRY B 124.18(2020):3743-3753.