Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation

doi:10.1021/acs.iecr.0c01320

	Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation
	Chen, Qiang 4,5; Li, Tianhao 5; Zhou, Yiming 5; Bi, Yunfei 1; Guo, Shuai 6; Liu, Xuan 5; Kang, Haozhe 5; Wang, Mengyue 5; Liu, Lei 6; Xing, Enhui 1
刊名	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
	2020-07-01
卷号	59 期号:26 页码:12004-12012
ISSN号	0888-5885
DOI	10.1021/acs.iecr.0c01320
英文摘要	Pt nanoparticles encapsulated into zeolite Y (denoted as Pt@Y) exhibited approaching 100% catalytic selectivity to 2,5-bis-(hydroxymethyl)-furan (BHMF) at full conversion of 5-hydroxymethylfurfural (HMF) in the presence of H-2, coupled with good reusability. Zeolite Y constrained HMF to be adsorbed on encapsulated Pt nanoparticle surface via either the end of aldehyde groups or hydroxyl groups in thermodynamically unfavorable end-on mode to enlarge the gap in the activation energies between hydrogenation of aldehyde groups and hydrodehydroxylation of hydroxyl groups to favor selectivity enhancement via avoidance of further hydrodehydroxylation at moderate conditions, which provide a general method to avoid thermodynamics-regulated flat-lying conformation for simultaneous activation on the furan ring, aldehyde, and hydroxyl groups.
资助项目	National Natural Science Foundation of China[21706204] ; National Natural Science Foundation of China[51972264] ; China Petroleum AMP; Chemical Corporation[119004-2] ; CAS Pioneer Hundred Talents Program
WOS关键词	TOTAL-ENERGY CALCULATIONS ; METAL-CLUSTERS ; CO OXIDATION ; NANOPARTICLES ; EFFICIENT ; SIZE ; NANOCRYSTALS ; DISPERSION ; CATALYSTS ; ATOMS
WOS研究方向	Engineering
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000547326800010
资助机构	National Natural Science Foundation of China ; China Petroleum AMP; Chemical Corporation ; CAS Pioneer Hundred Talents Program
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/41280]
专题	中国科学院过程工程研究所
通讯作者	Liu, Lei; Xing, Enhui; Yang, Dongyuan
作者单位	1.Sinopec, Res Inst Petr Proc, Beijing 100083, Peoples R China 2.Dalian Inst Chem Phys, Xian Clean Energy Chem Res Inst, Xian 710065, Shaanxi, Peoples R China 3.Shaanxi Yanchang Petr Grp Corp Ltd, Xian 710065, Shaanxi, Peoples R China 4.Sun Yat Sen Univ, Sch Chem Engn & Technol, Zhuh Ai 519082, Peoples R China 5.Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Shaanxi, Peoples R China 6.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Chen, Qiang,Li, Tianhao,Zhou, Yiming,et al. Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2020,59(26):12004-12012.
APA	Chen, Qiang.,Li, Tianhao.,Zhou, Yiming.,Bi, Yunfei.,Guo, Shuai.,...&Yang, Dongyuan.(2020).Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,59(26),12004-12012.
MLA	Chen, Qiang,et al."Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59.26(2020):12004-12012.