Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts

doi:10.1007/s11705-020-1932-y

	Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts
	Zhang, Jimei 2,3; Tian, Fuping 4; Chen, Junwen 1; Shi, Yanchun 3; Cao, Hongbin 3; Ning, Pengge 3; Sun, Shanshan 3; Xie, Yongbing 3
刊名	FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING
	2020-06-11
页码	11
关键词	aqueous-phase hydrodeoxygenation phenol hydrocarbons Ni/HIM-5 bi-functional catalyst
ISSN号	2095-0179
DOI	10.1007/s11705-020-1932-y
英文摘要	A series of Ni/HZSM-5 and Ni/HIM-5 bi-functional catalysts were synthesized and applied to the aqueous-phase hydrodeoxygenation (HDO) of phenol. The Ni dispersibility and particle sizes were shown to be directly related to the porosity and crystal sizes of the parent zeolites, which further influenced the catalytic performances. The large pores and small crystal sizes of the parent zeolites were beneficial for dispersing Ni and forming small Ni particles, and the corresponding Ni/zeolite catalyst exhibited a higher phenol conversion and selectivity towards hydrocarbons. Importantly, the Ni/HIM-5 bi-functional catalyst exhibited a high activity (98.3%) and high selectivity for hydrocarbons (98.8%) when heated at 220 degrees C for 1 h and is thus a new potential catalyst for the HDO of phenolics to form hydrocarbons in the aqueous phase.
资助项目	National Natural Science Foundation of China[21908225] ; National Key Research and Development Program of China[2016YFB0600505] ; Youth Innovation Promotion Association, CAS[2014037]
WOS关键词	MODEL-COMPOUND ; PALMITIC ACID ; SUPPORTED NI ; HYDRODEOXYGENATION ; LIGNIN ; BIOMASS ; PYROLYSIS ; HYDROCARBONS ; NI/HZSM-5 ; GUAIACOL
WOS研究方向	Engineering
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000539784400001
资助机构	National Natural Science Foundation of China ; National Key Research and Development Program of China ; Youth Innovation Promotion Association, CAS
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/41144]
专题	中国科学院过程工程研究所
通讯作者	Xie, Yongbing
作者单位	1.SINOPEC, Res Inst Petr Proc, State Key Lab Catalyt Mat & React Engn, Beijing 100083, Peoples R China 2.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 4.Dalian Univ Technol, Coll Chem, Dalian 116024, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Jimei,Tian, Fuping,Chen, Junwen,et al. Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts[J]. FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING,2020:11.
APA	Zhang, Jimei.,Tian, Fuping.,Chen, Junwen.,Shi, Yanchun.,Cao, Hongbin.,...&Xie, Yongbing.(2020).Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts.FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING,11.
MLA	Zhang, Jimei,et al."Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts".FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING (2020):11.