Ionic-Liquid-Based Bioisoprene Recovery Process Design

doi:10.1021/acs.iecr.0c00146

	Ionic-Liquid-Based Bioisoprene Recovery Process Design
	Chen, Yuqiu 2; Liu, Xinyan 1,2; Kontogeorgis, Georgios M.2; Woodley, John M.2
刊名	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
	2020-04-22
卷号	59 期号:16 页码:7355-7366
ISSN号	0888-5885
DOI	10.1021/acs.iecr.0c00146
英文摘要	Bioisoprene, which can be produced from renewable feedstocks through fermentation, is a promising alternative to petroleum-derived isoprene. However, challenges including the selection of feasible recovery techniques for bioisoprene should be addressed to achieve economic and technical competitiveness. In this work, ionic liquids (ILs) are first introduced as solvents for the recovery of bioisoprene. To describe the thermodynamic behavior, the UNIFAC-IL model is first extended to the bioisoprene systems as it combines gas-organic chemicals in IL-containing systems. Using a computer-aided IL design (CAILD) method, six out of 248 742 structurally constrained ILs are screened as optimal candidates for their further performance evaluation. Simulation results indicate that all six ILs have much better process performance than that of the alternative, isopropyl myrisate. Moreover, [N-1,N-1,N-3,N-0][DMP] is identified as the best IL with the lowest solvent flow rate and the highest recovery ratio of isoprene. This work shows the potential of using ILs for the recovery of bioisoprene from fermentation off-gas.
资助项目	China Scholarship Council[201708440264] ; Technical University of Denmark
WOS关键词	UNIFAC GROUP-CONTRIBUTION ; PRESSURE PHASE-BEHAVIOR ; COMPUTER-AIDED-DESIGN ; CARBON-DIOXIDE ; RENEWABLE ISOPRENE ; COSMO-RS ; SOLUBILITY ; CO2 ; MODEL ; PREDICTION
WOS研究方向	Engineering
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000529151200009
资助机构	China Scholarship Council ; Technical University of Denmark
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/40966]
专题	中国科学院过程工程研究所
通讯作者	Woodley, John M.
作者单位	1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China 2.Tech Univ Denmark, Dept Chem & Biochem Engn, DK-2800 Lyngby, Denmark
推荐引用方式 GB/T 7714	Chen, Yuqiu,Liu, Xinyan,Kontogeorgis, Georgios M.,et al. Ionic-Liquid-Based Bioisoprene Recovery Process Design[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2020,59(16):7355-7366.
APA	Chen, Yuqiu,Liu, Xinyan,Kontogeorgis, Georgios M.,&Woodley, John M..(2020).Ionic-Liquid-Based Bioisoprene Recovery Process Design.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,59(16),7355-7366.
MLA	Chen, Yuqiu,et al."Ionic-Liquid-Based Bioisoprene Recovery Process Design".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59.16(2020):7355-7366.