Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols | |
Cai, Guangming1,2; Yang, Shaoqi1,2; Wang, Xinxin1; Zhou, Qing1,2; Xu, Junli1; Lu, Xingmei1,2 | |
刊名 | JOURNAL OF SOLUTION CHEMISTRY |
2020-04-07 | |
页码 | 35 |
关键词 | Polyhydric protic ionic liquid Water Alcohols Density Viscosity |
ISSN号 | 0095-9782 |
DOI | 10.1007/s10953-020-00968-2 |
英文摘要 | 2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate ([BHEM] [mesy]) displayed good ability for separating cellulose from biomass material in previous works. In order to have a better understanding of the structure-property relationship and facilitate further potential applications in industry, it is necessary to obtain more data for the physicochemical properties of [BHEM][mesy] and its mixtures. In this work, the densities (.) and viscosities (.) of [BHEM][mesy] + solvents (water, methanol, ethanol, n-propanol and isopropanol) mixtures were measured at six temperatures from (298.15 to 323.15) K over the full molar composition range and fitted by an empirical quadratic equation and Vogel-Fucher-Tammann (VFT) equation. Moreover, the excess molar volumes (VE) and viscosity deviation (..) of five binary mixtures were calculated and correlated by the Redlich-Kister equation. In addition, the apparent molar volumes ( V) and partial molar volumes ( V) of [BHEM][mesy] and solvents were also calculated and all these physicochemical property data (density, viscosity, excess molar properties as well as the apparent molar properties) are discussed in terms of the structure and interaction of binary mixtures. |
资助项目 | National Natural Scientific Fund of China[21978291] ; National Natural Scientific Fund of China[21776289] ; National Natural Scientific Fund of China[21878292] ; National Natural Scientific Fund of China[21606240] ; K. C. Wong Education Foundation |
WOS关键词 | VAPOR-LIQUID-EQUILIBRIA ; HIGH-PRESSURE DENSITIES ; PLUS METHYL ACETATE ; THERMOPHYSICAL PROPERTIES ; 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE ; COMPOSITION DEPENDENCE ; VOLUMETRIC PROPERTIES ; ENZYMATIC-HYDROLYSIS ; SURFACE-TENSION ; MOLAR VOLUME |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | SPRINGER/PLENUM PUBLISHERS |
WOS记录号 | WOS:000524633500001 |
资助机构 | National Natural Scientific Fund of China ; K. C. Wong Education Foundation |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/40097] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Zhou, Qing; Lu, Xingmei |
作者单位 | 1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Cai, Guangming,Yang, Shaoqi,Wang, Xinxin,et al. Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols[J]. JOURNAL OF SOLUTION CHEMISTRY,2020:35. |
APA | Cai, Guangming,Yang, Shaoqi,Wang, Xinxin,Zhou, Qing,Xu, Junli,&Lu, Xingmei.(2020).Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols.JOURNAL OF SOLUTION CHEMISTRY,35. |
MLA | Cai, Guangming,et al."Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols".JOURNAL OF SOLUTION CHEMISTRY (2020):35. |
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