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Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols
Cai, Guangming1,2; Yang, Shaoqi1,2; Wang, Xinxin1; Zhou, Qing1,2; Xu, Junli1; Lu, Xingmei1,2
刊名JOURNAL OF SOLUTION CHEMISTRY
2020-04-07
页码35
关键词Polyhydric protic ionic liquid Water Alcohols Density Viscosity
ISSN号0095-9782
DOI10.1007/s10953-020-00968-2
英文摘要2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate ([BHEM] [mesy]) displayed good ability for separating cellulose from biomass material in previous works. In order to have a better understanding of the structure-property relationship and facilitate further potential applications in industry, it is necessary to obtain more data for the physicochemical properties of [BHEM][mesy] and its mixtures. In this work, the densities (.) and viscosities (.) of [BHEM][mesy] + solvents (water, methanol, ethanol, n-propanol and isopropanol) mixtures were measured at six temperatures from (298.15 to 323.15) K over the full molar composition range and fitted by an empirical quadratic equation and Vogel-Fucher-Tammann (VFT) equation. Moreover, the excess molar volumes (VE) and viscosity deviation (..) of five binary mixtures were calculated and correlated by the Redlich-Kister equation. In addition, the apparent molar volumes ( V) and partial molar volumes ( V) of [BHEM][mesy] and solvents were also calculated and all these physicochemical property data (density, viscosity, excess molar properties as well as the apparent molar properties) are discussed in terms of the structure and interaction of binary mixtures.
资助项目National Natural Scientific Fund of China[21978291] ; National Natural Scientific Fund of China[21776289] ; National Natural Scientific Fund of China[21878292] ; National Natural Scientific Fund of China[21606240] ; K. C. Wong Education Foundation
WOS关键词VAPOR-LIQUID-EQUILIBRIA ; HIGH-PRESSURE DENSITIES ; PLUS METHYL ACETATE ; THERMOPHYSICAL PROPERTIES ; 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE ; COMPOSITION DEPENDENCE ; VOLUMETRIC PROPERTIES ; ENZYMATIC-HYDROLYSIS ; SURFACE-TENSION ; MOLAR VOLUME
WOS研究方向Chemistry
语种英语
出版者SPRINGER/PLENUM PUBLISHERS
WOS记录号WOS:000524633500001
资助机构National Natural Scientific Fund of China ; K. C. Wong Education Foundation
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/40097]  
专题中国科学院过程工程研究所
通讯作者Zhou, Qing; Lu, Xingmei
作者单位1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Cai, Guangming,Yang, Shaoqi,Wang, Xinxin,et al. Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols[J]. JOURNAL OF SOLUTION CHEMISTRY,2020:35.
APA Cai, Guangming,Yang, Shaoqi,Wang, Xinxin,Zhou, Qing,Xu, Junli,&Lu, Xingmei.(2020).Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols.JOURNAL OF SOLUTION CHEMISTRY,35.
MLA Cai, Guangming,et al."Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols".JOURNAL OF SOLUTION CHEMISTRY (2020):35.
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