Modification to solution-diffusion model for performance prediction of nanofiltration of long-alkyl-chain ionic liquids aqueous solutions based on ion cluster

doi:10.1016/j.gee.2018.10.001

	Modification to solution-diffusion model for performance prediction of nanofiltration of long-alkyl-chain ionic liquids aqueous solutions based on ion cluster
	Qian, Jianguo 1,2; Yan, Ruiyi 1; Liu, Xiaomin 1; Li, Chunshan 1; Zhang, Xiangping 1
刊名	GREEN ENERGY & ENVIRONMENT
	2020
卷号	5 期号:1 页码:105-113
关键词	Solution-diffusion model Nanofiltration Long-alkyl-chain ionic liquid Molecular dynamic simulation Ion cluster
ISSN号	2096-2797
DOI	10.1016/j.gee.2018.10.001
英文摘要	Mathematical modeling for nanofiltration of ionic liquids (ILs) solutions could assist to understand transfer mechanism and predict experimental values. In this work, modeling by solution-diffusion model for nanofiltration of long-alkyl-chain ILs aqueous solutions was proposed. Molecular simulations were performed to validate the existence of ion cluster in long-alkyl-chain Its aqueous solution. Based on the results of simulations, parameters used in the solution-diffusion model were modified, such as concentration of ILs and diameter of ion cluster. The modeling process was developed for three long-alkyl-chain ILs aqueous solutions with different concentrations (1-alkyl-3-methylimidazolium chloride: [C(6)mim]Cl, [C(8)mim]Cl, [C(10)mim]Cl). The calculated values obtained from modified solution-diffusion model could well match the experimental values. (C) 2020, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd.
资助项目	National Key Research and Develop Program of China[2017YFA0206803] ; National Science Fund for Excellent Young Scholars[21722610] ; National Natural Science Foundation of China[21676277] ; National Natural Science Foundation of China[91434203] ; CAS-SAFEA International Partnership Program for Creative Research Teams[20140491518]
WOS关键词	MIXTURES ; ADSORPTION ; EXTRACTION ; SEPARATION ; MEMBRANES ; PRODUCTS ; BEHAVIOR ; LENGTH
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Energy & Fuels ; Engineering
语种	英语
出版者	KEAI PUBLISHING LTD
WOS记录号	WOS:000516829700013
资助机构	National Key Research and Develop Program of China ; National Science Fund for Excellent Young Scholars ; National Natural Science Foundation of China ; CAS-SAFEA International Partnership Program for Creative Research Teams
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/39662]
专题	中国科学院过程工程研究所
通讯作者	Li, Chunshan; Zhang, Xiangping
作者单位	1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Beijing Key Lab Ion Liq, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Qian, Jianguo,Yan, Ruiyi,Liu, Xiaomin,et al. Modification to solution-diffusion model for performance prediction of nanofiltration of long-alkyl-chain ionic liquids aqueous solutions based on ion cluster[J]. GREEN ENERGY & ENVIRONMENT,2020,5(1):105-113.
APA	Qian, Jianguo,Yan, Ruiyi,Liu, Xiaomin,Li, Chunshan,&Zhang, Xiangping.(2020).Modification to solution-diffusion model for performance prediction of nanofiltration of long-alkyl-chain ionic liquids aqueous solutions based on ion cluster.GREEN ENERGY & ENVIRONMENT,5(1),105-113.
MLA	Qian, Jianguo,et al."Modification to solution-diffusion model for performance prediction of nanofiltration of long-alkyl-chain ionic liquids aqueous solutions based on ion cluster".GREEN ENERGY & ENVIRONMENT 5.1(2020):105-113.