A mixed-valence Cu-II Cu-I coordination polymer based on bridged thiocyanate and in situ formed di(N-heterocyclic) sulfide Synthesis, structure, and magnetic properties

doi:10.1016/j.molstruc.2021.130623

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	A mixed-valence Cu-II Cu-I coordination polymer based on bridged thiocyanate and in situ formed di(N-heterocyclic) sulfide Synthesis, structure, and magnetic properties
	Cui, Yanfeng; Ding, Yuhan; Molina, Steven Eduardo Vilcacundo; Li, Yahong
刊名	JOURNAL OF MOLECULAR STRUCTURE
	2021
卷号	1241
ISSN号	0022-2860
DOI	10.1016/j.molstruc.2021.130623
英文摘要	A mixed-valence Cu-II/Cu-I coordination polymer {(CuCu2I)-Cu-II[S(PIP)(2)](mu-SCN)(4)}(n) (1) has been generated via the reaction of KSCN, CuCl2 center dot 2H(2)O, and 3-(pyridin-2-yl)imidazo[1,5-a]pyridine (HPIP) under solvothermal conditions. The di(N-heterocyclic) sulfide ligand [S(PIP)(2)] (S(PIP)(2) = bis(3-(pyridin-2-yl)imidazo[1,5-a]pyridin-1-yl)sulfane) was formed in situ by the reaction of HPIP and KSCN in the presence of CuCl2 center dot 2H(2)O. The structure of compound 1 was determined by X-ray single crystal diffraction. In the structure of 1 , one Cu-II ion, which is chelated by one neutral [S(PIP)(2)] ligand, and two Cu-I ions are connected by end-to-end thiocyanates to generate an infinite 2D coordination polymer. Complex 1 was also characterized by IR, PXRD, XPS and ESR. The magnetic properties of 1 have been investigated. (C) 2021 Elsevier B.V. All rights reserved.
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/34321]
专题	青海盐湖研究所_盐湖资源与化学实验室
推荐引用方式 GB/T 7714	Cui, Yanfeng,Ding, Yuhan,Molina, Steven Eduardo Vilcacundo,et al. A mixed-valence Cu-II Cu-I coordination polymer based on bridged thiocyanate and in situ formed di(N-heterocyclic) sulfide Synthesis, structure, and magnetic properties[J]. JOURNAL OF MOLECULAR STRUCTURE,2021,1241.
APA	Cui, Yanfeng,Ding, Yuhan,Molina, Steven Eduardo Vilcacundo,&Li, Yahong.(2021).A mixed-valence Cu-II Cu-I coordination polymer based on bridged thiocyanate and in situ formed di(N-heterocyclic) sulfide Synthesis, structure, and magnetic properties.JOURNAL OF MOLECULAR STRUCTURE,1241.
MLA	Cui, Yanfeng,et al."A mixed-valence Cu-II Cu-I coordination polymer based on bridged thiocyanate and in situ formed di(N-heterocyclic) sulfide Synthesis, structure, and magnetic properties".JOURNAL OF MOLECULAR STRUCTURE 1241(2021).