Characterization of a Novel Crown Ether System for Lithium Isotope Separation | |
Zhang, Zezheng; Jia, Yongzhong; Liu, Bing; Jing, Yan; Yao, Ying | |
刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH |
2021-09-08 | |
卷号 | 60期号:35页码:13031 |
ISSN号 | 0888-5885 |
DOI | 10.1021/acs.iecr.1c03245 |
英文摘要 | Li-6 and Li-7, with excellent nuclear properties, are important raw materials in the development of the nuclear industry. In the current work, a mercury-free extraction and lithium isotopic separation system with benzo-15-crown-5 (B15C5) ether as the extractant, ionic liquid as the co-extractant, and anisole as the diluent was constructed. In addition, a novel method for extracting lithium ions with B15C5 and multistage cross-flow separation of lithium isotopes by the organic liquid film were introduced. After 20 stages of cross-flow extraction, the abundance of Li-6 increased from 7.498 to 9.654% and the abundance of Li-7 increased from 92.502 to 93.561%. It was demonstrated that the B15C5 system not only can enrich Li-6 but also can serve to enrich Li-7. The reason for the enrichment of lithium isotopes by this method was explored. Moreover, this study predicted the number of theoretical cross-flow stages of the abundance of Li-6 and Li-7 which can be used as a nuclear material. |
内容类型 | 期刊论文 |
源URL | [http://ir.isl.ac.cn/handle/363002/34187] |
专题 | 青海盐湖研究所_盐湖资源综合利用工程技术中心 |
推荐引用方式 GB/T 7714 | Zhang, Zezheng,Jia, Yongzhong,Liu, Bing,et al. Characterization of a Novel Crown Ether System for Lithium Isotope Separation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2021,60(35):13031. |
APA | Zhang, Zezheng,Jia, Yongzhong,Liu, Bing,Jing, Yan,&Yao, Ying.(2021).Characterization of a Novel Crown Ether System for Lithium Isotope Separation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,60(35),13031. |
MLA | Zhang, Zezheng,et al."Characterization of a Novel Crown Ether System for Lithium Isotope Separation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 60.35(2021):13031. |
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