Influence of the pH in Reactions of Boric Acid Borax with Simple Hydroxyl Compounds Investigation by Raman Spectroscopy and DFT Calculations

doi:10.1002/slct.201903740

CORC > 青海盐湖研究所 > 中国科学院青海盐湖研究所 > 盐湖资源与化学实验室

	Influence of the pH in Reactions of Boric Acid Borax with Simple Hydroxyl Compounds Investigation by Raman Spectroscopy and DFT Calculations
	Bai, Chun; Wu, Zhijian; Ye, Xiushen; Liu, Haining; Liu, Zhong; Zhang, Huifang; Li, Quan; Li, Jun; Wang, Xuming
刊名	CHEMISTRYSELECT
	2019-12-30
卷号	4 期号:48 页码:14132-1419
ISSN号	2365-6549
DOI	10.1002/slct.201903740
英文摘要	The complexation of Boric acid/Borax with hydroxyl compounds is an effective means for the removal and separation of boron in solutions. In this paper, the pH values of the solutions having different molar ratios of boron to hydroxyl compounds including Ethanol, isopropanol, Propanol, 1,2 propanediol, 2,3 butanediol, Glycerol, Xylitol, D-fructose, D-sorbitol, and D-mannitol were determined and analyzed to study the reaction of Boric acid/Borax with different hydroxyl compounds. Solution Raman spectroscopy and DFT calculation were performed to confirm the observations. It was found that the complexation of borate with hydroxyl alcohols follow the order of monohydric alcohols < dihydric and trihydric alcohols < polyols. For polyols, the OH configuration plays very important role in the complexation, and xylitol has the strongest complexation among the polyols at the same molar ratios of boron to polyols.
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/34126]
专题	青海盐湖研究所_盐湖资源与化学实验室中国科学院青海盐湖研究所
推荐引用方式 GB/T 7714	Bai, Chun,Wu, Zhijian,Ye, Xiushen,et al. Influence of the pH in Reactions of Boric Acid Borax with Simple Hydroxyl Compounds Investigation by Raman Spectroscopy and DFT Calculations[J]. CHEMISTRYSELECT,2019,4(48):14132-1419.
APA	Bai, Chun.,Wu, Zhijian.,Ye, Xiushen.,Liu, Haining.,Liu, Zhong.,...&Wang, Xuming.(2019).Influence of the pH in Reactions of Boric Acid Borax with Simple Hydroxyl Compounds Investigation by Raman Spectroscopy and DFT Calculations.CHEMISTRYSELECT,4(48),14132-1419.
MLA	Bai, Chun,et al."Influence of the pH in Reactions of Boric Acid Borax with Simple Hydroxyl Compounds Investigation by Raman Spectroscopy and DFT Calculations".CHEMISTRYSELECT 4.48(2019):14132-1419.