One-pot synthesis and hierarchical assembly of hollow Cu2O microspheres with nanocrystals-composed porous multishell and their gas-sensing properties | |
Zhang, Huigang; Zhu, Qingshan; Zhang, Yang; Wang, Yong; Zhao, Li; Yu, Bin | |
刊名 | ADVANCED FUNCTIONAL MATERIALS |
2007-10-15 | |
卷号 | 17期号:15页码:2766-2771 |
关键词 | lithium-ion batteries solution route spheres architecture nanospheres growth sensor metal nanostructures organization |
ISSN号 | 1616-301X |
其他题名 | Adv. Funct. Mater. |
中文摘要 | Hierarchical assembly of hollow microstructures is of great scientific and practical value and remains a great challenge. This paper presents a facile and one-pot synthesis of Cu2O microspheres with multilayered and porous shells, which were organized by nanocrystals. The time-dependent experiments revealed a two-step organization process, in which hollow microspheres of Cu-2(OH)(3)NO3 were formed first due to the Ostwald ripening and then reduced by glutamic acid, the resultant Cu2O nanocrystals were deposited on the hollow intermediate microspheres and organized into finally multishell structures. The special microstructures actually recorded the evolution process of materials morphologies and microstructures in space and time scales, implying an intermediate-templating route, which is important for understanding and fabricating complex architectures. The Cu2O microspheres obtained were used to fabricate a gas sensor, which showed much higher sensitivity than solid C(u)2O microspheres. |
英文摘要 | Hierarchical assembly of hollow microstructures is of great scientific and practical value and remains a great challenge. This paper presents a facile and one-pot synthesis of Cu2O microspheres with multilayered and porous shells, which were organized by nanocrystals. The time-dependent experiments revealed a two-step organization process, in which hollow microspheres of Cu-2(OH)(3)NO3 were formed first due to the Ostwald ripening and then reduced by glutamic acid, the resultant Cu2O nanocrystals were deposited on the hollow intermediate microspheres and organized into finally multishell structures. The special microstructures actually recorded the evolution process of materials morphologies and microstructures in space and time scales, implying an intermediate-templating route, which is important for understanding and fabricating complex architectures. The Cu2O microspheres obtained were used to fabricate a gas sensor, which showed much higher sensitivity than solid C(u)2O microspheres. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
关键词[WOS] | LITHIUM-ION BATTERIES ; SOLUTION ROUTE ; SPHERES ; ARCHITECTURE ; NANOSPHERES ; GROWTH ; SENSOR ; METAL ; NANOSTRUCTURES ; ORGANIZATION |
收录类别 | SCI |
原文出处 | |
语种 | 英语 |
WOS记录号 | WOS:000250526300019 |
公开日期 | 2013-10-15 |
内容类型 | 期刊论文 |
版本 | 出版稿 |
源URL | [http://ir.ipe.ac.cn/handle/122111/3514] |
专题 | 过程工程研究所_研究所(批量导入) |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Multiphase React Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Elect, State Key Lab Transducer Technol, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Huigang,Zhu, Qingshan,Zhang, Yang,et al. One-pot synthesis and hierarchical assembly of hollow Cu2O microspheres with nanocrystals-composed porous multishell and their gas-sensing properties[J]. ADVANCED FUNCTIONAL MATERIALS,2007,17(15):2766-2771. |
APA | Zhang, Huigang,Zhu, Qingshan,Zhang, Yang,Wang, Yong,Zhao, Li,&Yu, Bin.(2007).One-pot synthesis and hierarchical assembly of hollow Cu2O microspheres with nanocrystals-composed porous multishell and their gas-sensing properties.ADVANCED FUNCTIONAL MATERIALS,17(15),2766-2771. |
MLA | Zhang, Huigang,et al."One-pot synthesis and hierarchical assembly of hollow Cu2O microspheres with nanocrystals-composed porous multishell and their gas-sensing properties".ADVANCED FUNCTIONAL MATERIALS 17.15(2007):2766-2771. |
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