A transparent electrode with water-oxidizing activity

doi:10.1016/j.ijhydene.2018.10.146

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	A transparent electrode with water-oxidizing activity
	Azadi, Gouhar ; Bagheri, Robabeh 6; Bikas, Rahman 7; Mousazade, Younes ; Cui, Junfeng 3,8; Song, Zhenlun 6; Kinzhybalo, Vasyl 5; Shen, Jian-Ren ; Allakhverdiev, Suleyman I.; Najafpour, Mohammad Mahdi 1,16
刊名	INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
	2018
卷号	43 期号:51 页码:22896-22904
关键词	Water oxidation Hydrogen production Fluorine-doped tin oxide Catalyst
ISSN号	0360-3199
DOI	10.1016/j.ijhydene.2018.10.146
文献子类	Article
英文摘要	Hydrogen production by water splitting is a promising method to store energy. Water-oxidation reaction is a bottleneck in water-splitting systems. Herein, a mononuclear nickel(II) phosphine complex with 1,2-bis(dicyclohexylphosphino)ethane ligand, was synthesized and characterized by X-ray crystallography method. The water-oxidizing catalyst under the electrochemical condition was studied. The role of Ni compound for the water-oxidation reaction on the surface of fluorine-doped tin oxide as one of the true catalysts was investigated by the electrochemical methods and Scanning Electron Microscopy coupled with Energy Dispersive X-ray (SEM/EDX) Spectroscopy. The big ligand around the Ni ion causes a very small size of Ni-based particles on the surface of the electrode, which are the active catalysts for the water-oxidation reaction. Such small nanosized Ni-based compounds are transparent and have no effect on the transparency of the obtained fluorine-doped tin oxide. Thus, it is a promising method to synthesize a transparent fluorine-doped tin oxide with water-oxidizing activity. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
学科主题	Chemistry, Physical ; Electrochemistry ; Energy & Fuels
电子版国际标准刊号	1879-3487
出版地	OXFORD
WOS关键词	OXIDATION CATALYSTS ; SINGLE-CRYSTALS ; MANGANESE OXIDE ; NICKEL ; COMPLEX ; EFFICIENT ; TETRAFLUOROBORATE ; ELECTROCATALYSTS ; PALLADIUM ; INSIGHTS
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000453642500011
资助机构	Iran National Science Foundation (INSF)Iran National Science Foundation (INSF) [95007330] ; Institute for Advanced Studies in Basic Sciences, Imam Khomeini International University ; Polish Academy of Science [24000018] ; JSPS, MEXT, JapanMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science [24000018] ; Russian Science FoundationRussian Science Foundation (RSF) [14-14-00039]
内容类型	期刊论文
源URL	[http://ir.ibcas.ac.cn/handle/2S10CLM1/20616]
专题	中科院光生物学重点实验室
作者单位	1.IASBS, Ctr Climate Change & Global Warming, Zanjan 4513766731, Iran 2.IASBS, Res Ctr Basic Sci & Modern Technol RBST, Zanjan 4513766731, Iran 3.Dalian Univ Technol, Key Lab Precis & Nontradit Machining Technol, Minist Educ, Dalian 116024, Peoples R China 4.Polish Acad Sci, Inst Low Temp & Struct Res, PL-50422 Wroclaw, Poland 5.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China 6.IASBS, Dept Chem, Zanjan 4513766731, Iran 7.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Surface Dept, Surface Protect Res Grp, 519 Zhuangshi Rd, Ningbo 315201, Zhejiang, Peoples R China 8.Imam Khomeini Int Univ, Dept Chem, Fac Sci, Qazvin 3414896818, Iran 9.Chinese Acad Sci, Inst Bot, Photosynth Res Ctr, Key Lab Photobiol, 20 Nanxincun, Beijing 100093, Peoples R China 10.Allakhverdiev, Suleyman I.] Russian Acad Sci, Inst Plant Physiol, Controlled Photobiosynth Lab, Bot Skaya St 35, Moscow 127276, Russia
推荐引用方式 GB/T 7714	Azadi, Gouhar,Bagheri, Robabeh,Bikas, Rahman,et al. A transparent electrode with water-oxidizing activity[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2018,43(51):22896-22904.
APA	Azadi, Gouhar.,Bagheri, Robabeh.,Bikas, Rahman.,Mousazade, Younes.,Cui, Junfeng.,...&Najafpour, Mohammad Mahdi.(2018).A transparent electrode with water-oxidizing activity.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,43(51),22896-22904.
MLA	Azadi, Gouhar,et al."A transparent electrode with water-oxidizing activity".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 43.51(2018):22896-22904.