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Influence of Microdefect Size on Corrosion Behavior of Epoxy-Coated Rebar for Application in Seawater-Mixed Concrete
Wan, Li1,2; Wei, Yinghua1; Zhao, Hongtao1; Cao, Haijiao1; Li, Jing1
刊名COATINGS
2021-04-01
卷号11期号:4页码:25
关键词corrosion epoxy-coated rebar seawater-mixed concrete microdefect LEIS SVET
DOI10.3390/coatings11040439
通讯作者Wei, Yinghua(yhwei@imr.ac.cn)
英文摘要Corrosion behavior of epoxy-coated rebar with different size of microdefects in uncarbonated/carbonated simulated pore solution (U/CSPS) of seawater concrete was investigated. Specimens in both solutions underwent two stages of corrosion, according to the electrochemical impedance spectroscopy (EIS) response. The initial stage was the extension of corrosion. The second stage was dominated by the diffusion process, due to the corrosion products blocking the defects and hindering the transportation of the reaction matter. Local electrochemical impedance spectroscopy (LEIS), scanning vibrating electrode technique (SVET) measurements and the observation of corrosion products indicated that 50 mu m might be the threshold, because the corrosion of specimens with defects bigger than 50 mu m in diameter was significantly more severe. Crevice corrosion was identified to occur in the experiments. The corrosion products of specimens in USPS and CSPS were mainly Fe3O4 and FeOOH, respectively. alpha-FeOOH and beta-FeOOH exhibited an anion ion-selective property in the corrosion process, which induced crevice corrosion in CSPS. In particular, it is contended herein that Fe3O4 has the cation ion-selective property to protect the substrate in USPS.
资助项目Strategic Precursor Research Program of the Chinese Academy of Sciences[XDA13040501] ; National Natural Science Foundation of China[52071320]
WOS研究方向Materials Science ; Physics
语种英语
出版者MDPI
WOS记录号WOS:000642932500001
资助机构Strategic Precursor Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/162439]  
专题金属研究所_中国科学院金属研究所
通讯作者Wei, Yinghua
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
推荐引用方式
GB/T 7714
Wan, Li,Wei, Yinghua,Zhao, Hongtao,et al. Influence of Microdefect Size on Corrosion Behavior of Epoxy-Coated Rebar for Application in Seawater-Mixed Concrete[J]. COATINGS,2021,11(4):25.
APA Wan, Li,Wei, Yinghua,Zhao, Hongtao,Cao, Haijiao,&Li, Jing.(2021).Influence of Microdefect Size on Corrosion Behavior of Epoxy-Coated Rebar for Application in Seawater-Mixed Concrete.COATINGS,11(4),25.
MLA Wan, Li,et al."Influence of Microdefect Size on Corrosion Behavior of Epoxy-Coated Rebar for Application in Seawater-Mixed Concrete".COATINGS 11.4(2021):25.
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