Influence of Microdefect Size on Corrosion Behavior of Epoxy-Coated Rebar for Application in Seawater-Mixed Concrete | |
Wan, Li1,2; Wei, Yinghua1; Zhao, Hongtao1; Cao, Haijiao1; Li, Jing1 | |
刊名 | COATINGS |
2021-04-01 | |
卷号 | 11期号:4页码:25 |
关键词 | corrosion epoxy-coated rebar seawater-mixed concrete microdefect LEIS SVET |
DOI | 10.3390/coatings11040439 |
通讯作者 | Wei, Yinghua(yhwei@imr.ac.cn) |
英文摘要 | Corrosion behavior of epoxy-coated rebar with different size of microdefects in uncarbonated/carbonated simulated pore solution (U/CSPS) of seawater concrete was investigated. Specimens in both solutions underwent two stages of corrosion, according to the electrochemical impedance spectroscopy (EIS) response. The initial stage was the extension of corrosion. The second stage was dominated by the diffusion process, due to the corrosion products blocking the defects and hindering the transportation of the reaction matter. Local electrochemical impedance spectroscopy (LEIS), scanning vibrating electrode technique (SVET) measurements and the observation of corrosion products indicated that 50 mu m might be the threshold, because the corrosion of specimens with defects bigger than 50 mu m in diameter was significantly more severe. Crevice corrosion was identified to occur in the experiments. The corrosion products of specimens in USPS and CSPS were mainly Fe3O4 and FeOOH, respectively. alpha-FeOOH and beta-FeOOH exhibited an anion ion-selective property in the corrosion process, which induced crevice corrosion in CSPS. In particular, it is contended herein that Fe3O4 has the cation ion-selective property to protect the substrate in USPS. |
资助项目 | Strategic Precursor Research Program of the Chinese Academy of Sciences[XDA13040501] ; National Natural Science Foundation of China[52071320] |
WOS研究方向 | Materials Science ; Physics |
语种 | 英语 |
出版者 | MDPI |
WOS记录号 | WOS:000642932500001 |
资助机构 | Strategic Precursor Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/162439] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Wei, Yinghua |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China |
推荐引用方式 GB/T 7714 | Wan, Li,Wei, Yinghua,Zhao, Hongtao,et al. Influence of Microdefect Size on Corrosion Behavior of Epoxy-Coated Rebar for Application in Seawater-Mixed Concrete[J]. COATINGS,2021,11(4):25. |
APA | Wan, Li,Wei, Yinghua,Zhao, Hongtao,Cao, Haijiao,&Li, Jing.(2021).Influence of Microdefect Size on Corrosion Behavior of Epoxy-Coated Rebar for Application in Seawater-Mixed Concrete.COATINGS,11(4),25. |
MLA | Wan, Li,et al."Influence of Microdefect Size on Corrosion Behavior of Epoxy-Coated Rebar for Application in Seawater-Mixed Concrete".COATINGS 11.4(2021):25. |
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