Electrochemical deposition as a universal route for fabricating single-atom catalysts

doi:10.1038/s41467-020-14917-6

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Electrochemical deposition as a universal route for fabricating single-atom catalysts
	Zhang, ZR ; Feng, C ; Liu, CX ; Zuo, M ; Qin, L ; Yan, XP ; Xing, YL ; Li, HL ; Si, R ; Zhou, SM
刊名	NATURE COMMUNICATIONS
	2020
卷号	11 期号:1 页码:-
关键词	OXYGEN SITES PLATINUM PERFORMANCE NANOSHEETS OXIDATION EFFICIENT METHANOL DOPANTS WATER
ISSN号	2041-1723
DOI	10.1038/s41467-020-14917-6
文献子类	期刊论文
英文摘要	Single-atom catalysts (SACs) exhibit intriguing catalytic performance owing to their maximized atom utilizations and unique electronic structures. However, the reported strategies for synthesizing SACs generally have special requirements for either the anchored metals or the supports. Herein, we report a universal approach of electrochemical deposition that is applicable to a wide range of metals and supports for the fabrication of SACs. The depositions were conducted on both cathode and anode, where the different redox reactions endowed the SACs with distinct electronic states. The SACs from cathodic deposition exhibited high activities towards hydrogen evolution reaction, while those from anodic deposition were highly active towards oxygen evolution reaction. When cathodically- and anodically-deposited Ir single atoms on Co0.8Fe0.2Se2@Ni foam were integrated into a two-electrode cell for overall water splitting, a voltage of 1.39V was required at 10mAcm(-2) in alkaline electrolyte. While single-atom catalysts exhibit intriguing catalytic performances and electronic structures, syntheses are often tailored to a particular system. Here, authors report electrochemical deposition as a universal approach for the fabrication of single-atom catalysts over range of metals and supports.
语种	英语
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/32839]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位	1.Univ Sci & Technol China, Chinese Acad Sci,Key Lab Strongly Coupled Quantum, Anhui Higher Educ Inst,Key Lab Surface & Interfac, Hefei Natl Lab Phys Sci Microscale,Dept Chem Phys, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
推荐引用方式 GB/T 7714	Zhang, ZR,Feng, C,Liu, CX,et al. Electrochemical deposition as a universal route for fabricating single-atom catalysts[J]. NATURE COMMUNICATIONS,2020,11(1):-.
APA	Zhang, ZR.,Feng, C.,Liu, CX.,Zuo, M.,Qin, L.,...&Zeng, J.(2020).Electrochemical deposition as a universal route for fabricating single-atom catalysts.NATURE COMMUNICATIONS,11(1),-.
MLA	Zhang, ZR,et al."Electrochemical deposition as a universal route for fabricating single-atom catalysts".NATURE COMMUNICATIONS 11.1(2020):-.